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Statements

Subject Item
n2:RIV%2F00023272%3A_____%2F14%3A%230002415%21RIV15-MK0-00023272
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Raman spectra of two well-defined types of cobaltkoritnigite and koritnigite crystals were recorded and interpreted. Significant differences in the Raman spectra of cobaltkoritnigite and koritnigite were observed. Observed Raman bands were attributed to the (AsO3OH)2 stretching and bending vibrations, stretching and bending vibrations of water molecules and hydroxyl ions. Both Raman and infrared spectra of cobaltkoritnigite identify bands which are attributable to phosphate and hydrogen phosphate anions proving some substitution of phosphate for arsenate in the structure of cobaltkoritnigite. The O-H ... O hydrogen bond lengths in the crystal structure of koritnigite were inferred from the Raman spectra and compared with those derived from the X-ray single crystal refinement. Raman spectra of two well-defined types of cobaltkoritnigite and koritnigite crystals were recorded and interpreted. Significant differences in the Raman spectra of cobaltkoritnigite and koritnigite were observed. Observed Raman bands were attributed to the (AsO3OH)2 stretching and bending vibrations, stretching and bending vibrations of water molecules and hydroxyl ions. Both Raman and infrared spectra of cobaltkoritnigite identify bands which are attributable to phosphate and hydrogen phosphate anions proving some substitution of phosphate for arsenate in the structure of cobaltkoritnigite. The O-H ... O hydrogen bond lengths in the crystal structure of koritnigite were inferred from the Raman spectra and compared with those derived from the X-ray single crystal refinement.
dcterms:title
A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite
skos:prefLabel
A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite
skos:notation
RIV/00023272:_____/14:#0002415!RIV15-MK0-00023272
n3:aktivita
n6:V
n3:aktivity
V
n3:cisloPeriodika
May
n3:dodaniDat
n4:2015
n3:domaciTvurceVysledku
n12:9440828 n12:2244306
n3:druhVysledku
n10:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
1276
n3:idVysledku
RIV/00023272:_____/14:#0002415
n3:jazykVysledku
n13:eng
n3:klicovaSlova
koritnigite; cobaltokoritnigite; arsenates; Raman spectroscopy
n3:klicoveSlovo
n5:Raman%20spectroscopy n5:arsenates n5:koritnigite n5:cobaltokoritnigite
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[B5B7A9BC2FA6]
n3:nazevZdroje
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
n3:obor
n16:DB
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
8
n3:rokUplatneniVysledku
n4:2014
n3:svazekPeriodika
125
n3:tvurceVysledku
Frost, Ray Leslie Souza, Larissa Čejka, Jiří Scholz, Ricardo Xi, Yunfei Sejkora, Jiří Cristiano, Lana López, Andrés
n3:wos
000334898700040
s:issn
1386-1425
s:numberOfPages
6
n11:doi
10.1016/j.saa.2014.01.106