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Statements

Subject Item
n2:RIV%2F00023272%3A_____%2F14%3A%230002394%21RIV15-MK0-00023272
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Raman spectra of two well-defined ferrimolybdite samples, Fe2(MoO4)3. 7-8H2O, from the Krupka deposit (northern Bohemia, Czech Republic) and Hurky near Rakovnik occurrence (central Bohemia, Czech Republic) were studied and tentatively interpreted. Observed bands were assigned to the stretching and bending vibrations of molybdate anions, Fe-O units and water molecules. Number of Raman and infrared bands assigned to (MoO4) units and water molecules proved that symmetrically (structurally) nonequivalent (MoO4) and H2O are present in the crystal structure of ferrimolybdite. Approximate O-H ... O hydrogen bond lengths (2.80-2.73 angstrom) were inferred from the published infrared spectra. Raman spectra of two well-defined ferrimolybdite samples, Fe2(MoO4)3. 7-8H2O, from the Krupka deposit (northern Bohemia, Czech Republic) and Hurky near Rakovnik occurrence (central Bohemia, Czech Republic) were studied and tentatively interpreted. Observed bands were assigned to the stretching and bending vibrations of molybdate anions, Fe-O units and water molecules. Number of Raman and infrared bands assigned to (MoO4) units and water molecules proved that symmetrically (structurally) nonequivalent (MoO4) and H2O are present in the crystal structure of ferrimolybdite. Approximate O-H ... O hydrogen bond lengths (2.80-2.73 angstrom) were inferred from the published infrared spectra.
dcterms:title
A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O
skos:prefLabel
A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O
skos:notation
RIV/00023272:_____/14:#0002394!RIV15-MK0-00023272
n3:aktivita
n15:I
n3:aktivity
I
n3:cisloPeriodika
September
n3:dodaniDat
n5:2015
n3:domaciTvurceVysledku
n12:2244306 n12:5225140 n12:9440828
n3:druhVysledku
n4:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
1085
n3:idVysledku
RIV/00023272:_____/14:#0002394
n3:jazykVysledku
n13:eng
n3:klicovaSlova
ferrimolybdite; Raman spectroscopy; molybdate; water molecules
n3:klicoveSlovo
n10:water%20molecules n10:molybdate n10:Raman%20spectroscopy n10:ferrimolybdite
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[D67AD6E17620]
n3:nazevZdroje
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
n3:obor
n9:DB
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
6
n3:rokUplatneniVysledku
n5:2014
n3:svazekPeriodika
130
n3:tvurceVysledku
Čejka, Jiří López, Andrés Sejkora, Jiří Malíková, Radana Xi, Yunfei Frost, Ray Leslie
n3:wos
000338806800013
s:issn
1386-1425
s:numberOfPages
7
n17:doi
10.1016/j.saa.2014.03.112