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Statements

Subject Item
n2:RIV%2F00023272%3A_____%2F11%3A%230001564%21RIV12-MK0-00023272
rdf:type
n9:Vysledek skos:Concept
dcterms:description
Raman and infrared spectra of two polymorphous minerals with the chemical formula Fe3+(SO4)(OH). 2H2O, monoclinic butlerite and orthorhombic parabutlerite, are studied and the spectra assigned. Observed bands are attributed to the (SO4)2- stretching and bending vibrations, hydrogen bonded water molecules, stretching and bending vibrations of hydroxyl ions, water librational modes, Fe-O and Fe-OH stretching vibrations, Fe-OH bending vibrations and lattice vibrations. The O-H ... O hydrogen bond lengths in the structures of both minerals are calculated from the wavenumbers of the stretching vibrations. One symmetrically distinct (SO4)2- unit in the structure of butlerite and two symmetrically distinct (SO4)2- units in the structure of parabutlerite are inferred from the Raman and infrared spectra. This conclusion agrees with the published crystal structures of both mineral phases. Raman and infrared spectra of two polymorphous minerals with the chemical formula Fe3+(SO4)(OH). 2H2O, monoclinic butlerite and orthorhombic parabutlerite, are studied and the spectra assigned. Observed bands are attributed to the (SO4)2- stretching and bending vibrations, hydrogen bonded water molecules, stretching and bending vibrations of hydroxyl ions, water librational modes, Fe-O and Fe-OH stretching vibrations, Fe-OH bending vibrations and lattice vibrations. The O-H ... O hydrogen bond lengths in the structures of both minerals are calculated from the wavenumbers of the stretching vibrations. One symmetrically distinct (SO4)2- unit in the structure of butlerite and two symmetrically distinct (SO4)2- units in the structure of parabutlerite are inferred from the Raman and infrared spectra. This conclusion agrees with the published crystal structures of both mineral phases.
dcterms:title
A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite
skos:prefLabel
A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite
skos:notation
RIV/00023272:_____/11:#0001564!RIV12-MK0-00023272
n9:predkladatel
n10:ico%3A00023272
n3:aktivita
n19:Z n19:I
n3:aktivity
I, Z(MK00002327201)
n3:cisloPeriodika
5
n3:dodaniDat
n12:2012
n3:domaciTvurceVysledku
n11:2244306 n11:9440828 n11:4767543
n3:druhVysledku
n6:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n8:predkladatel
n3:idSjednocenehoVysledku
184251
n3:idVysledku
RIV/00023272:_____/11:#0001564
n3:jazykVysledku
n4:eng
n3:klicovaSlova
butlerite; parabutlerite; iron (III) sulfates; Raman spectroscopy; Infrared spectroscopy
n3:klicoveSlovo
n15:parabutlerite n15:butlerite n15:iron%20%28III%29%20sulfates n15:Infrared%20spectroscopy n15:Raman%20spectroscopy
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[B0C3E2FEB775]
n3:nazevZdroje
Spectrochimica Acta Part A-Molecular and biomolecular spectroscopy
n3:obor
n14:DB
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
6
n3:rokUplatneniVysledku
n12:2011
n3:svazekPeriodika
79
n3:tvurceVysledku
Bahfenne, Silmarilly Palmer, Sara J. Čejka, Jiří Sejkora, Jiří Frost, Ray Leslie Plášil, Jakub
n3:wos
000293363000076
n3:zamer
n17:MK00002327201
s:issn
1386-1425
s:numberOfPages
8
n16:doi
10.1016/j.saa.2011.04.069