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Statements

Subject Item
n2:RIV%2F00023272%3A_____%2F08%3A%230000997%21RIV10-MK0-00023272
rdf:type
n13:Vysledek skos:Concept
dcterms:description
Raman and infrared spectra of the uranyl mineral zellerite, Ca[(UO2)(CO3)2(H2O)2] 3H2O, were measured and tentatively interpreted. U-O bond in uranyl and O-H center dot center dot center dot O hydrogen bonds were calculated from the vibrational spectra. The presence of structurally nonequivalent water molecules in the crystal structure of zellerite was inferred. A proposed chemical formula of zellerite is supported. Raman bands at 3514, 3375 and 2945 cm-1 and broad infrared bands at 3513, 3396 and 3326 cm-1 are related to the v OH stretching vibrations of hydrogen-bonded water molecules. Observed wavenumbers of these vibrations prove that in fact hydrogen bonds participate in the crystal structure of zellerite. The presence of two bands at 1618 and 1681 cm-1 proves structurally distinct and nonequivalent water molecules in the crystal structure of zellerite. Raman and infrared spectra of the uranyl mineral zellerite, Ca[(UO2)(CO3)2(H2O)2] 3H2O, were measured and tentatively interpreted. U-O bond in uranyl and O-H center dot center dot center dot O hydrogen bonds were calculated from the vibrational spectra. The presence of structurally nonequivalent water molecules in the crystal structure of zellerite was inferred. A proposed chemical formula of zellerite is supported. Raman bands at 3514, 3375 and 2945 cm-1 and broad infrared bands at 3513, 3396 and 3326 cm-1 are related to the v OH stretching vibrations of hydrogen-bonded water molecules. Observed wavenumbers of these vibrations prove that in fact hydrogen bonds participate in the crystal structure of zellerite. The presence of two bands at 1618 and 1681 cm-1 proves structurally distinct and nonequivalent water molecules in the crystal structure of zellerite.
dcterms:title
Raman spectroscopic study of the uranyl carbonate mineral zellerite Raman spectroscopic study of the uranyl carbonate mineral zellerite
skos:prefLabel
Raman spectroscopic study of the uranyl carbonate mineral zellerite Raman spectroscopic study of the uranyl carbonate mineral zellerite
skos:notation
RIV/00023272:_____/08:#0000997!RIV10-MK0-00023272
n4:aktivita
n15:V
n4:aktivity
V
n4:cisloPeriodika
5
n4:dodaniDat
n10:2010
n4:domaciTvurceVysledku
n9:2244306
n4:druhVysledku
n5:J
n4:duvernostUdaju
n16:S
n4:entitaPredkladatele
n12:predkladatel
n4:idSjednocenehoVysledku
391438
n4:idVysledku
RIV/00023272:_____/08:#0000997
n4:jazykVysledku
n11:eng
n4:klicovaSlova
zellerite; uranyl minerals; carbonates; Raman spectroscopy; infrared spectroscopy; mineralogy
n4:klicoveSlovo
n7:carbonates n7:mineralogy n7:Raman%20spectroscopy n7:infrared%20spectroscopy n7:zellerite n7:uranyl%20minerals
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[BF6E7A18BCD3]
n4:nazevZdroje
Journal of Raman Spectroscopy
n4:obor
n8:DB
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
3
n4:rokUplatneniVysledku
n10:2008
n4:svazekPeriodika
39
n4:tvurceVysledku
Dickfos, Marilla J. Čejka, Jiří Frost, Ray Leslie
n4:wos
000256167200005
s:issn
0377-0486
s:numberOfPages
5