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Statements

Subject Item
n2:RIV%2F00023272%3A_____%2F08%3A%230000996%21RIV10-MK0-00023272
rdf:type
n7:Vysledek skos:Concept
dcterms:description
The mineral marthozite, a uranyl selenite, has been characterised by Raman spectroscopy at 298 K. The bands at 812 and 797 cm-1 were assigned to the symmetric stretching modes of the (UO2)2+ and (SeO3)2 units, respectively. These values gave the calculated U-O bond lengths in uranyl of 1.799 and/or 1.814 angstrom. Average U-O bond length in uranyl is 1.795 angstrom, inferred from the X-ray single crystal structure analysis of marthozite by Cooper and Hawthorne. The broad band at 869 cm-1 was assigned to the v(3) antisymmetric stretching mode of the (UO2)2+ (calculated U-O bond length 1.808 angstrom). The band at 739 cm-1 was attributed to the v(3) antisymmetric stretching vibration of the (SeO3)2- units. The v(4) and the v(2) vibrational modes of the (SeO3)2- units were observed at 424 and 473 cm-1. The mineral marthozite, a uranyl selenite, has been characterised by Raman spectroscopy at 298 K. The bands at 812 and 797 cm-1 were assigned to the symmetric stretching modes of the (UO2)2+ and (SeO3)2 units, respectively. These values gave the calculated U-O bond lengths in uranyl of 1.799 and/or 1.814 angstrom. Average U-O bond length in uranyl is 1.795 angstrom, inferred from the X-ray single crystal structure analysis of marthozite by Cooper and Hawthorne. The broad band at 869 cm-1 was assigned to the v(3) antisymmetric stretching mode of the (UO2)2+ (calculated U-O bond length 1.808 angstrom). The band at 739 cm-1 was attributed to the v(3) antisymmetric stretching vibration of the (SeO3)2- units. The v(4) and the v(2) vibrational modes of the (SeO3)2- units were observed at 424 and 473 cm-1.
dcterms:title
Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O
skos:prefLabel
Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O
skos:notation
RIV/00023272:_____/08:#0000996!RIV10-MK0-00023272
n4:aktivita
n10:V
n4:aktivity
V
n4:cisloPeriodika
10
n4:dodaniDat
n11:2010
n4:domaciTvurceVysledku
n12:2244306
n4:druhVysledku
n15:J
n4:duvernostUdaju
n9:S
n4:entitaPredkladatele
n13:predkladatel
n4:idSjednocenehoVysledku
391441
n4:idVysledku
RIV/00023272:_____/08:#0000996
n4:jazykVysledku
n16:eng
n4:klicovaSlova
marthozite; uranyl minerals; selenites; Raman spectroscopy; mineralogy
n4:klicoveSlovo
n5:marthozite n5:selenites n5:Raman%20spectroscopy n5:uranyl%20minerals n5:mineralogy
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[10AD1CA53584]
n4:nazevZdroje
Journal of Raman Spectroscopy
n4:obor
n8:DB
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
4
n4:rokUplatneniVysledku
n11:2008
n4:svazekPeriodika
39
n4:tvurceVysledku
Frost, Ray Leslie Keeffe, Eloise C. Dickfos, Marilla J. Čejka, Jiří
n4:wos
000260355900014
s:issn
0377-0486
s:numberOfPages
6