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Statements

Subject Item
n2:RIV%2F00023272%3A_____%2F08%3A%230000994%21RIV10-MK0-00023272
rdf:type
skos:Concept n10:Vysledek
dcterms:description
Raman spectroscopy, complemented with infrared spectroscopy, was used to study the uranyl carbonate mineral voglite. The mineral has the formula Ca2Cu2+ [(UO2)(CO3)(3)](CO3)6H(2)O, and bands attributed to these vibrating units are readily identified in the Raman spectrum. Symmetric stretching modes at 836 and 1094 cm(-1) are assigned to nu(1)(UO2)(2+) and nu(1)(CO3)(2-) units, respectively. The nu(3) antisymmetric stretching modes of (UO2)(2+) are not observed in the Raman spectrum but may be readily observed in the infrared spectrum at 898 cm(-1). The nu(3) antisymmetric stretching mode of (CO3)(2-) is observed in the Raman spectrum at 1369 cm(-1) as a low intensity band as is also the nu(3)(CO3)(2-) infrared modes at 1362, 1425, 1509 and 1566 cm(-1). No nu(2)(CO3)(2-) Raman bending modes are observed for voglite. Raman spectroscopy, complemented with infrared spectroscopy, was used to study the uranyl carbonate mineral voglite. The mineral has the formula Ca2Cu2+ [(UO2)(CO3)(3)](CO3)6H(2)O, and bands attributed to these vibrating units are readily identified in the Raman spectrum. Symmetric stretching modes at 836 and 1094 cm(-1) are assigned to nu(1)(UO2)(2+) and nu(1)(CO3)(2-) units, respectively. The nu(3) antisymmetric stretching modes of (UO2)(2+) are not observed in the Raman spectrum but may be readily observed in the infrared spectrum at 898 cm(-1). The nu(3) antisymmetric stretching mode of (CO3)(2-) is observed in the Raman spectrum at 1369 cm(-1) as a low intensity band as is also the nu(3)(CO3)(2-) infrared modes at 1362, 1425, 1509 and 1566 cm(-1). No nu(2)(CO3)(2-) Raman bending modes are observed for voglite.
dcterms:title
Raman spectroscopic study of the uranyl carbonate mineral voglite Raman spectroscopic study of the uranyl carbonate mineral voglite
skos:prefLabel
Raman spectroscopic study of the uranyl carbonate mineral voglite Raman spectroscopic study of the uranyl carbonate mineral voglite
skos:notation
RIV/00023272:_____/08:#0000994!RIV10-MK0-00023272
n3:aktivita
n13:V
n3:aktivity
V
n3:cisloPeriodika
3
n3:dodaniDat
n8:2010
n3:domaciTvurceVysledku
n14:2244306
n3:druhVysledku
n11:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
391437
n3:idVysledku
RIV/00023272:_____/08:#0000994
n3:jazykVysledku
n6:eng
n3:klicovaSlova
uranyl carbonate; voglite; Jáchymov; mineralogy; Raman spectroscopy
n3:klicoveSlovo
n5:mineralogy n5:uranyl%20carbonate n5:Raman%20spectroscopy n5:J%C3%A1chymov n5:voglite
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[650B5A743AAE]
n3:nazevZdroje
Journal of Raman Spectroscopy
n3:obor
n15:DB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n8:2008
n3:svazekPeriodika
39
n3:tvurceVysledku
Ayoko, Godwin Čejka, Jiří Dickfos, Marilla J. Frost, Ray Leslie
n3:wos
000254586500011
s:issn
0377-0486
s:numberOfPages
6