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Statements

Subject Item
n2:0878
rdf:type
n4:Projekt
dcterms:description
Cílem projektu je příprava nových krystalických materiálů pro NLO aplikace vycházejících z organických kationtů, které jsou ve struktuře vhodně fixovány sítí aniontů, a jejich detailní charakterizace metodami difrakčními, spektroskopickými, kalorimetrickými a optickými (zvláště kvantifikace SHG). Main goal of the proposed project is the preparation and study of novel crystalline materials for non-linear optics. Target group of compounds can be defined as salts of selected organic cations (carriers of NLO properties), which are properly fixed by anions or their networks in crystal structures (via hydrogen bonds). Unsaturated molecules with system of delocalized electrons e.g. nitrogen containing heteroaromatic bases or Y-aromatic molecules (derivatives of guanidine and biguanide) are selected as promising cations. Besides of well-established inorganic oxy-acids, dicarboxylic acids (especially chiral tartaric and malic acids) will be employed for the formation of H-bonded anionic networks. Novel materials will be characterized by the methods of X-ray diffraction, vibrational, electron and NMR spectroscopy and DSC. Optical characterization will be mainly focused on efficiency of second harmonic generation. Obtained novel materials can be technically utilized in the field of optical computing and data storage and telecommunications.
dcterms:title
Crystal engineering of hydrogen bonded materials for non-linear optics Krystalové inženýrství materiálů s vodíkovými vazbami pro nelineární optiku
n4:cislo-smlouvy
n6:0878
n4:dalsi-vedlejsi-obor
n7:CA
n4:druh-souteze
n5:VS
n4:faze
n9:52808234
n4:hlavni-obor
n7:CF
n4:vedlejsi-obor
n7:CC
n4:id-aktivity
n11:GA
n4:id-souteze
n13:SGA02009GA-ST
n4:kategorie
n10:1
n4:klicova-slova
nelineární optika, vodíkové vazby, krystalové inženýrství, generování 2. harmonické frekvence, vibra
n4:konec-reseni
2011-12-31+01:00
n4:pocet-koordinujicich-prijemcu
0
n4:poskytovatel
n8:GA0
n4:start-reseni
2009-01-01+01:00
n4:statni-podpora
2481
n4:typProjektu
n12:P
n4:uznane-naklady
2481
n4:pocet-prijemcu
1
n4:pocet-spoluprijemcu
1
n4:pocet-vysledku
23
n4:pocet-vysledku-zverejnovanych
23