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Description
  • A method for the determination of pressure-affected viscosity from capillary rheometry and pressure-volume-temperature (PVT) data was tested on polyphenylsulfone melt. Shear viscosity data evaluated at selected temperatures (345-375°C) were interlinked to the PVT data at pressures ranging from 1 to 200 MPa. According to the recently proposed correlation approach, a pressure-dependent shear viscosity is derived from the relationship (verified on several commodity polymers) between temperature-dependent viscosity and a free volume parameter computed using the Simha-Somcynsky equation of state. Finally, the predicted pressure-viscosity coefficient was compared with the value obtained experimentally on a modified single piston rheometer.
  • A method for the determination of pressure-affected viscosity from capillary rheometry and pressure-volume-temperature (PVT) data was tested on polyphenylsulfone melt. Shear viscosity data evaluated at selected temperatures (345-375°C) were interlinked to the PVT data at pressures ranging from 1 to 200 MPa. According to the recently proposed correlation approach, a pressure-dependent shear viscosity is derived from the relationship (verified on several commodity polymers) between temperature-dependent viscosity and a free volume parameter computed using the Simha-Somcynsky equation of state. Finally, the predicted pressure-viscosity coefficient was compared with the value obtained experimentally on a modified single piston rheometer. (en)
Title
  • An evaluation of the pressure-dependent melt viscosity of polyphenylsulfone
  • An evaluation of the pressure-dependent melt viscosity of polyphenylsulfone (en)
skos:prefLabel
  • An evaluation of the pressure-dependent melt viscosity of polyphenylsulfone
  • An evaluation of the pressure-dependent melt viscosity of polyphenylsulfone (en)
skos:notation
  • RIV/70883521:28610/14:43871540!RIV15-MSM-28610___
http://linked.open...avai/riv/aktivita
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  • I, P(ED2.1.00/03.0111), P(GA103/08/1307)
http://linked.open...iv/cisloPeriodika
  • 3
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  • 2468
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  • RIV/70883521:28610/14:43871540
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  • Simha-Somcynsky equation; PVT; shear viscosity; polyphenylsulfone (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [12630208B336]
http://linked.open...i/riv/nazevZdroje
  • Polymer Engineering and Science
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http://linked.open...v/svazekPeriodika
  • 54
http://linked.open...iv/tvurceVysledku
  • Filip, Petr
  • Sedláček, Tomáš
  • Hausnerová, Berenika
issn
  • 0032-3888
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/pen.23604
http://localhost/t...ganizacniJednotka
  • 28610
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