About: Time-Resolved Study of the Photo-Curing Process of Dental Resins with the NMR-MOUSE     Goto   Sponge   NotDistinct   Permalink

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  • The photo-curing reaction of dental resins has been examined with unilateral nuclear magnetic resonance (NMR-MOUSE) allowing nondestructive high-resolution measurement of depth profiles as a function of time and space. The NMR signal is sensitive to both the monomer concentration and changes in molecular mobility. Upon irradiation with blue light, it first increases due to molecular mobility enhanced by the reaction heat and then decreases exponentially with the monomer concentration as the polymer signal is lost in the dead time of the instrument upon curing. The space and time dependence of the NMR signal can be described by the photo-polymerization reaction kinetics together with a heuristic approximation of the temperature dependence.
  • The photo-curing reaction of dental resins has been examined with unilateral nuclear magnetic resonance (NMR-MOUSE) allowing nondestructive high-resolution measurement of depth profiles as a function of time and space. The NMR signal is sensitive to both the monomer concentration and changes in molecular mobility. Upon irradiation with blue light, it first increases due to molecular mobility enhanced by the reaction heat and then decreases exponentially with the monomer concentration as the polymer signal is lost in the dead time of the instrument upon curing. The space and time dependence of the NMR signal can be described by the photo-polymerization reaction kinetics together with a heuristic approximation of the temperature dependence. (en)
Title
  • Time-Resolved Study of the Photo-Curing Process of Dental Resins with the NMR-MOUSE
  • Time-Resolved Study of the Photo-Curing Process of Dental Resins with the NMR-MOUSE (en)
skos:prefLabel
  • Time-Resolved Study of the Photo-Curing Process of Dental Resins with the NMR-MOUSE
  • Time-Resolved Study of the Photo-Curing Process of Dental Resins with the NMR-MOUSE (en)
skos:notation
  • RIV/70883521:28610/13:43869979!RIV14-MSM-28610___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED2.1.00/03.0111)
http://linked.open...iv/cisloPeriodika
  • 9
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 111124
http://linked.open...ai/riv/idVysledku
  • RIV/70883521:28610/13:43869979
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • visible light curing, dental composites, curing behaviour, NMR:MOUSE (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • AT - Rakouská republika
http://linked.open...ontrolniKodProRIV
  • [95F6295E4306]
http://linked.open...i/riv/nazevZdroje
  • Applied Magnetic Resonance
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 44
http://linked.open...iv/tvurceVysledku
  • Hausnerová, Berenika
  • Moeginger, Bernhard
  • Steinhaus, Johannes
  • Blümich, Bernhard
  • Marchi Netto, Antonio
http://linked.open...ain/vavai/riv/wos
  • 000322648200004
issn
  • 0937-9347
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s00723-013-0458-6
http://localhost/t...ganizacniJednotka
  • 28610
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