About: Cross-Linking of Ethylene-Octene Copolymer (EOC) by Dicumyl Peroxide (DCP)     Goto   Sponge   NotDistinct   Permalink

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  • Ethylene-octene copolymer (EOC) was crosslinked by dicumyl peroxide (DCP) at various temperatures (150–200°C). Six concentrations of DCP in range 0.2–0.7 wt % were investigated. cross-linking was studied by rubber process analyzer (RPA) and by differential scanning calorimetry (DSC). From RPA data analysis real part modulus s', tan δ, and reaction rate were investigated as a function of peroxide content and temperature. The highest s'max and the lowest tan δ were found for 0.7% of DCP at 150°C. Chain scission was analyzed by slope analysis of conversion ratio, X in times after reaching the maximum. Less susceptible to chain scission are temperatures in range 150–170°C and peroxide levels 0.2–0.5%. Heat of reaction was analyzed by DSC at various heating rates (5–40°C °C/min). It was found to be exothermic. By projection to zero heating rate, the reaction was found to start at 128°C with the maximum at 168°C.
  • Ethylene-octene copolymer (EOC) was crosslinked by dicumyl peroxide (DCP) at various temperatures (150–200°C). Six concentrations of DCP in range 0.2–0.7 wt % were investigated. cross-linking was studied by rubber process analyzer (RPA) and by differential scanning calorimetry (DSC). From RPA data analysis real part modulus s', tan δ, and reaction rate were investigated as a function of peroxide content and temperature. The highest s'max and the lowest tan δ were found for 0.7% of DCP at 150°C. Chain scission was analyzed by slope analysis of conversion ratio, X in times after reaching the maximum. Less susceptible to chain scission are temperatures in range 150–170°C and peroxide levels 0.2–0.5%. Heat of reaction was analyzed by DSC at various heating rates (5–40°C °C/min). It was found to be exothermic. By projection to zero heating rate, the reaction was found to start at 128°C with the maximum at 168°C. (en)
Title
  • Cross-Linking of Ethylene-Octene Copolymer (EOC) by Dicumyl Peroxide (DCP)
  • Cross-Linking of Ethylene-Octene Copolymer (EOC) by Dicumyl Peroxide (DCP) (en)
skos:prefLabel
  • Cross-Linking of Ethylene-Octene Copolymer (EOC) by Dicumyl Peroxide (DCP)
  • Cross-Linking of Ethylene-Octene Copolymer (EOC) by Dicumyl Peroxide (DCP) (en)
skos:notation
  • RIV/70883521:28150/11:43865339!RIV12-MSM-28150___
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • Z(MSM7088352102)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
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http://linked.open...dnocenehoVysledku
  • 192309
http://linked.open...ai/riv/idVysledku
  • RIV/70883521:28150/11:43865339
http://linked.open...riv/jazykVysledku
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  • DSC; RPA; chain scission; cross-linking; dicumyl peroxide; ethylene-octene copolymer (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [CD0CDA3517C0]
http://linked.open...i/riv/nazevZdroje
  • Journal of Applied Polymer Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 121
http://linked.open...iv/tvurceVysledku
  • Inoue, Takashi
  • Kolomazník, Karel
  • Mokrejš, Pavel
  • Ougizawa, Toshiaki
  • Poongavalappil, Sameepa
  • Svoboda, Petr
  • Svobodová, Dagmar
  • Theravalappil, Rajesh
http://linked.open...ain/vavai/riv/wos
  • 000289353700063
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-8995
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/app.33655
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  • 28150
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