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  • Titanium oxide/polypyrrole (TiO2/PPy) particles with core-shell structure were synthesized as a novel dispersed phase for electrorheological (ER) suspensions in this study. Core of these composite particles was prepared from TiO2 nanoparticles via simple and rapid microwave-assisted molten-salt synthesis and, subsequently, coated with conducting polymer polypyrrole via an oxidative polymerization forming a shell. The structural composition and morphology of prepared particles were examined with X-Ray diffraction (XRD) analysis and scanning electron microscopy (SEM), respectively. The XRD revealed increase in the rutile phase of TiO2 after the synthesis while SEM proved the formation of micrometer-sized rod-like particles. The ER activity of suspensions of prepared rod-like TiO2 particles and their PPy-coated variant was examined using a rotational rheometer under various electric field strengths. It was found that polypyrrole coating significantly improves the ER performance as was also confirmed via dielectric spectroscopy.
  • Titanium oxide/polypyrrole (TiO2/PPy) particles with core-shell structure were synthesized as a novel dispersed phase for electrorheological (ER) suspensions in this study. Core of these composite particles was prepared from TiO2 nanoparticles via simple and rapid microwave-assisted molten-salt synthesis and, subsequently, coated with conducting polymer polypyrrole via an oxidative polymerization forming a shell. The structural composition and morphology of prepared particles were examined with X-Ray diffraction (XRD) analysis and scanning electron microscopy (SEM), respectively. The XRD revealed increase in the rutile phase of TiO2 after the synthesis while SEM proved the formation of micrometer-sized rod-like particles. The ER activity of suspensions of prepared rod-like TiO2 particles and their PPy-coated variant was examined using a rotational rheometer under various electric field strengths. It was found that polypyrrole coating significantly improves the ER performance as was also confirmed via dielectric spectroscopy. (en)
Title
  • Electrorheological properties of suspensions of rod-like titanium oxide/polypyrrole particles
  • Electrorheological properties of suspensions of rod-like titanium oxide/polypyrrole particles (en)
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  • Electrorheological properties of suspensions of rod-like titanium oxide/polypyrrole particles
  • Electrorheological properties of suspensions of rod-like titanium oxide/polypyrrole particles (en)
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  • RIV/70883521:28110/12:43869372!RIV13-MSM-28110___
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  • P(ED2.1.00/03.0111), S
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  • RIV/70883521:28110/12:43869372
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  • Microwave; Rod-like; Polypyrrole; Titanium oxide; Core-shell; Electrorheology (en)
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  • XLIX
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  • Kuřitka, Ivo
  • Mrlík, Miroslav
  • Pavlínek, Vladimír
  • Sedlačík, Michal
  • Almajdalawi, Shawqi
  • Kozáková, Věra
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  • 28110
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