About: Structure changes of electrorheological fluids based on polyaniline particles with various hydrophilicities and time dependence of shear stress and conductivity during flow     Goto   Sponge   NotDistinct   Permalink

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  • Particles of polyaniline protonated with perfluorooctanesulfonic acid provided a material with hydrophobic surface. This property enabled its perfect dispersion in silicone oil due to its good compatibility with the hydrophobic medium. In contrast, in a suspension of hydrophilic polyaniline particles doped with sulfamic acid, strong interactions of particles prevailed, which led to the formation of entangled chains of aggregated particles in suspension. The difference in structural properties of suspensions exists already in the absence of electric field and significantly influences their electrorheological behavior after application of electric field. The formation of electrorheological structure has been monitored by recording time dependences of the shear stress and the electric current passing through the flowing suspensions.
  • Particles of polyaniline protonated with perfluorooctanesulfonic acid provided a material with hydrophobic surface. This property enabled its perfect dispersion in silicone oil due to its good compatibility with the hydrophobic medium. In contrast, in a suspension of hydrophilic polyaniline particles doped with sulfamic acid, strong interactions of particles prevailed, which led to the formation of entangled chains of aggregated particles in suspension. The difference in structural properties of suspensions exists already in the absence of electric field and significantly influences their electrorheological behavior after application of electric field. The formation of electrorheological structure has been monitored by recording time dependences of the shear stress and the electric current passing through the flowing suspensions. (en)
Title
  • Structure changes of electrorheological fluids based on polyaniline particles with various hydrophilicities and time dependence of shear stress and conductivity during flow
  • Structure changes of electrorheological fluids based on polyaniline particles with various hydrophilicities and time dependence of shear stress and conductivity during flow (en)
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  • Structure changes of electrorheological fluids based on polyaniline particles with various hydrophilicities and time dependence of shear stress and conductivity during flow
  • Structure changes of electrorheological fluids based on polyaniline particles with various hydrophilicities and time dependence of shear stress and conductivity during flow (en)
skos:notation
  • RIV/70883521:28110/11:43865347!RIV12-MSM-28110___
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  • P(GA202/09/1626), Z(MSM7088352101)
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  • 4
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  • 232797
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  • RIV/70883521:28110/11:43865347
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  • Hydrophilicity, Hydrophobicity, Electrorheology, Polyaniline suspension, Protonation, Conductivity, Time dependence (en)
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  • US - Spojené státy americké
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  • [72DBA0ED14FF]
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  • Colloid & Polymer Science
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  • 289
http://linked.open...iv/tvurceVysledku
  • Pavlínek, Vladimír
  • Quadrat, Otakar
  • Stejskal, Jaroslav
  • Stěnička, Martin
  • Sáha, Petr
  • Blinova, Natalia V.
http://linked.open...ain/vavai/riv/wos
  • 000287506700008
http://linked.open...n/vavai/riv/zamer
issn
  • 0303-402X
number of pages
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  • 10.1007/s00396-010-2357-9
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  • 28110
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