About: Transmission Electron Microscopy Study of Phase Morphology in Polypropylene/Ethylene-Octene Copolymer Blends     Goto   Sponge   NotDistinct   Permalink

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  • Blends of polypropylene (PP) and ethylene-octene copolymers (EOC) were investigated by transmission electron microscopy (TEM) and by differential scanning calorimetry (DSC). The EOC contained 28, 37, 40 or 52 wt.% of octene. Only the 50/50 PP/EOC ratio was used for all blends. None of the blends was fully miscible, there was always two-phase morphology. TEM observation followed by image analysis by ImageJ software revealed that the largest particles were in blend containing EOC-28 and the smallest were in blend with EOC-52. The coarsening rate at 200°C was evaluated by TEM. The glass transition temperature (Tg) shift indicated partial miscibility. Partial miscibility was then confirmed by direct observation of bright PP lamellae in EOC dark phase.
  • Blends of polypropylene (PP) and ethylene-octene copolymers (EOC) were investigated by transmission electron microscopy (TEM) and by differential scanning calorimetry (DSC). The EOC contained 28, 37, 40 or 52 wt.% of octene. Only the 50/50 PP/EOC ratio was used for all blends. None of the blends was fully miscible, there was always two-phase morphology. TEM observation followed by image analysis by ImageJ software revealed that the largest particles were in blend containing EOC-28 and the smallest were in blend with EOC-52. The coarsening rate at 200°C was evaluated by TEM. The glass transition temperature (Tg) shift indicated partial miscibility. Partial miscibility was then confirmed by direct observation of bright PP lamellae in EOC dark phase. (en)
Title
  • Transmission Electron Microscopy Study of Phase Morphology in Polypropylene/Ethylene-Octene Copolymer Blends
  • Transmission Electron Microscopy Study of Phase Morphology in Polypropylene/Ethylene-Octene Copolymer Blends (en)
skos:prefLabel
  • Transmission Electron Microscopy Study of Phase Morphology in Polypropylene/Ethylene-Octene Copolymer Blends
  • Transmission Electron Microscopy Study of Phase Morphology in Polypropylene/Ethylene-Octene Copolymer Blends (en)
skos:notation
  • RIV/70883521:28110/09:63508039!RIV10-MSM-28110___
http://linked.open...avai/riv/aktivita
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  • Z(MSM7088352102)
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  • 45
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  • 346774
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  • RIV/70883521:28110/09:63508039
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  • polypropylene; ethylene-octene copolymer; phase morphology (en)
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  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [B42373C1FBC2]
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  • European Polymer Journal
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  • Inoue, Takashi
  • Ougizawa, Toshiaki
  • Svoboda, Petr
  • Svobodová, Dagmar
  • Slobodián, Petr
http://linked.open...ain/vavai/riv/wos
  • 000266230000018
http://linked.open...n/vavai/riv/zamer
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  • 0014-3057
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  • 28110
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