About: The diffusion process of sodium hyaluronate (Na-HA) and Na-HA-n-alkyl derivatives films swelling     Goto   Sponge   NotDistinct   Permalink

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Description
  • Byl studován difuzní proces bobtnání hyaluronanu jeho hydrofobně modifikovaných derivátů (alkyl deriváty) vodou. Kinetika tohoto procesu byla studována pomocí tzv. interferometrické metody. Na základě měřené kinetiky bylo možné vypočítat vzájemný difuzní koeficient a srovnat jednotlivé vzorky derivátů. Vzorky byly měřeny při třech teplotách (25, 37 a 45°C). Následně byly spočítány aktivační entalpie difuze expanzní práce při přechodu polymerního klubka z pevné fáze do gelové povrchové vrstvy. (cs)
  • The process of diffusion of sodium hyaluronate and its hydrophobically modified alkyl derivatives in water was studied by measuring the kinetics of solid polymer film swelling. The following fundamental thermodynamic parameters of the swelling process were calculated: the apparent diffusion coefficient of swelling by water Ds determined at three temperatures (25, 37 and 45°C), the activation enthalpy of diffusion connected with the swelling HD,s and the activation enthalpy of the swelling process Hs. The thermodynamic activity of the solvent for the given sodium hyaluronate and its four alkyl derivatives has been expressed through the internal quantity RA,s, i.e. expansion work of polymer coil accomplished by the action of the internal pressure.
  • The process of diffusion of sodium hyaluronate and its hydrophobically modified alkyl derivatives in water was studied by measuring the kinetics of solid polymer film swelling. The following fundamental thermodynamic parameters of the swelling process were calculated: the apparent diffusion coefficient of swelling by water Ds determined at three temperatures (25, 37 and 45°C), the activation enthalpy of diffusion connected with the swelling HD,s and the activation enthalpy of the swelling process Hs. The thermodynamic activity of the solvent for the given sodium hyaluronate and its four alkyl derivatives has been expressed through the internal quantity RA,s, i.e. expansion work of polymer coil accomplished by the action of the internal pressure. (en)
Title
  • The diffusion process of sodium hyaluronate (Na-HA) and Na-HA-n-alkyl derivatives films swelling
  • Difuzní proces bobtnání hyaluronanu a jeho alkylových derivátů (cs)
  • The diffusion process of sodium hyaluronate (Na-HA) and Na-HA-n-alkyl derivatives films swelling (en)
skos:prefLabel
  • The diffusion process of sodium hyaluronate (Na-HA) and Na-HA-n-alkyl derivatives films swelling
  • Difuzní proces bobtnání hyaluronanu a jeho alkylových derivátů (cs)
  • The diffusion process of sodium hyaluronate (Na-HA) and Na-HA-n-alkyl derivatives films swelling (en)
skos:notation
  • RIV/70883521:28110/07:63505303!RIV08-MSM-28110___
http://linked.open.../vavai/riv/strany
  • 184-190
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM7088352101)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 417318
http://linked.open...ai/riv/idVysledku
  • RIV/70883521:28110/07:63505303
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • hyaluronan; HA-n-alkyl derivatives; Hydrophobic modification; swelling; activation enthalpy; diffusion process of swelling; sodium hyaluronate (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [293E7D112198]
http://linked.open...i/riv/nazevZdroje
  • Journal of Biomedical Materials Research. Part A
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 83A
http://linked.open...iv/tvurceVysledku
  • Benešová, Karolína
  • Lapčík, Lubomír
  • Urban, Pavel
  • Minařík, Antonín
  • Mráček, Aleš
http://linked.open...n/vavai/riv/zamer
issn
  • 1549-3296
number of pages
http://localhost/t...ganizacniJednotka
  • 28110
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