About: Effect of diluent on the gel point and mechanical properties of polyurethane networks

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Gel point conversions and equilibrium tensile moduli of polyester-based polyurethane networks were determined for different dilutions during network formation. Also, the limiting dilution beyond which the network was not formed at full conversion of functional groups was determined. It ranged between 92 and 94% of diluent. The scaling dependences against the reference states – the ring-free case and the limiting dilution case – showed that the excluded volume effects were operative and structural changes associated with cyclization affected the rates of both the intramolecular and the intermolecular reactions. Gel point conversions and equilibrium tensile moduli of polyester-based polyurethane networks were determined for different dilutions during network formation. Also, the limiting dilution beyond which the network was not formed at full conversion of functional groups was determined. It ranged between 92 and 94% of diluent. The scaling dependences against the reference states – the ring-free case and the limiting dilution case – showed that the excluded volume effects were operative and structural changes associated with cyclization affected the rates of both the intramolecular and the intermolecular reactions. (en)
Title	Effect of diluent on the gel point and mechanical properties of polyurethane networks Effect of diluent on the gel point and mechanical properties of polyurethane networks (en)
skos:prefLabel	Effect of diluent on the gel point and mechanical properties of polyurethane networks Effect of diluent on the gel point and mechanical properties of polyurethane networks (en)
skos:notation	RIV/70883521:28110/07:43865782!RIV12-MSM-28110___
http://linked.open...avai/riv/aktivita	V Z
http://linked.open...avai/riv/aktivity	V, Z(AV0Z40500505), Z(MSM0021620835)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Ďuračková, Andrea
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Tomáše Bati ve Zlíně / Fakulta technologická
http://linked.open...dnocenehoVysledku	418900
http://linked.open...ai/riv/idVysledku	RIV/70883521:28110/07:43865782
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	networks; polyurethane; properties; mechanical; point; diluent; Effect (en)
http://linked.open.../riv/klicoveSlovo	diluent mechanical networks properties Effect polyurethane point
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[227D1B2AA64B]
http://linked.open...i/riv/nazevZdroje	Polymer Bulletin
http://linked.open...in/vavai/riv/obor	BM
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	58
http://linked.open...iv/tvurceVysledku	Dušek, Karel Valentová, Helena Dušková-Smrčková, Miroslava Ďuračková, Andrea
http://linked.open...ain/vavai/riv/wos	000243051200021
http://linked.open...n/vavai/riv/zamer	Progresivní makromolekulární materiály a supramolekulární systémy: syntéza a studium vlastností, jevů a možností využití pro speciální aplikace a moderní technologie Fyzika molekulárních, makromolekulárních a biologických systémů
issn	0170-0839
number of pages	11 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s00289-006-0589-0
http://localhost/t...ganizacniJednotka	28110
is http://linked.open...avai/riv/vysledek of	Effect of diluent on the gel point and mechanical properties of polyurethane networks

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