About: 3-Thiocyanato-2,4(1H,3H)-Quinolinediones- an Effective Thiocyanating Agents     Goto   Sponge   NotDistinct   Permalink

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Description
  • 3-Thiocyanato-2,4(1H,3H-)quinolinediones react with water to give 4-hydroxy-2(1H)-quinolin-2-ones and hypothiocyanous acid. Also other nucleophiles attact title compounds at the sulfur atom and thiocyanato group in transferred to nucleophile. By this manner, S-cyanothiohydroxylamines were prepared from aliphatic aminex, p-thiocyanatoanilines from anilines, and alfa-thiocyanato derivatives from Wittig reagents. Thiols are oxidized to disulfides.
  • 3-Thiocyanato-2,4(1H,3H-)quinolinediones react with water to give 4-hydroxy-2(1H)-quinolin-2-ones and hypothiocyanous acid. Also other nucleophiles attact title compounds at the sulfur atom and thiocyanato group in transferred to nucleophile. By this manner, S-cyanothiohydroxylamines were prepared from aliphatic aminex, p-thiocyanatoanilines from anilines, and alfa-thiocyanato derivatives from Wittig reagents. Thiols are oxidized to disulfides. (en)
Title
  • 3-Thiocyanato-2,4(1H,3H)-Quinolinediones- an Effective Thiocyanating Agents
  • 3-Thiocyanato-2,4(1H,3H)-Quinolinediones- an Effective Thiocyanating Agents (en)
skos:prefLabel
  • 3-Thiocyanato-2,4(1H,3H)-Quinolinediones- an Effective Thiocyanating Agents
  • 3-Thiocyanato-2,4(1H,3H)-Quinolinediones- an Effective Thiocyanating Agents (en)
skos:notation
  • RIV/70883521:28110/02:63500554!RIV/2003/MSM/281103/N
http://linked.open.../vavai/riv/strany
  • 166
http://linked.open...avai/riv/aktivita
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  • Z(MSM 265200015)
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  • 671963
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  • RIV/70883521:28110/02:63500554
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  • thiocyanation, S-cyanothiohydroxylamines, p-thiocyanatoanilines, disulfides (en)
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http://linked.open...ontrolniKodProRIV
  • [8184D698E007]
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  • Tatranská Lomnica
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  • Bratislava
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  • 9th Blue Danube Symposium on Heterocyclic Chemistry - book of abstracts
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  • Klásek, Antonín
  • Mrkvička, Vladimír
  • Košmrlj, J.
  • Polis, Jiří
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http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Slovenská technická univerzita v Bratislave. Vydavateľstvo STU
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  • 80-227-1705-3
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  • 28110
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