About: Influence of diluent alkyl substituion on the extraction of Am(III) and Eu(III) by a 6,6'-bis(1,2,4-triazin-3-yl)-2,2'-bipyridine ligand dissolved in alkylated cyclohexanone diluents

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About: Influence of diluent alkyl substituion on the extraction of Am(III) and Eu(III) by a 6,6'-bis(1,2,4-triazin-3-yl)-2,2'-bipyridine ligand dissolved in alkylated cyclohexanone diluents Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The paper describes the influence of alkyl substitution on the extraction of Am(III) and Eu(III) by CyMe4-BTBP ligand dissolved in different cyclohexanone derivatives. Several alkylated cyclohexanones were investigated as potential diluents for the selective extraction of Am(III) from Eu(III) from nitric acid solutions by the CyMe4-BTBP ligand. No significant extraction of either of the metal ions was observed for these diluents themselves. In the extractions from 1 M HNO3, 3-methylcyclohexanone and 4-methylcyclohexanone gave comparable results to cyclohexanone. However, alkyl substitution of cyclohexanone significantly slows down the extraction kinetics compared to cyclohexanone, and the position of alkyl substitution was found to play an important role in the solvents properties. 3-Methylcyclohexanone was identified as the most promising of the diluents. The paper describes the influence of alkyl substitution on the extraction of Am(III) and Eu(III) by CyMe4-BTBP ligand dissolved in different cyclohexanone derivatives. Several alkylated cyclohexanones were investigated as potential diluents for the selective extraction of Am(III) from Eu(III) from nitric acid solutions by the CyMe4-BTBP ligand. No significant extraction of either of the metal ions was observed for these diluents themselves. In the extractions from 1 M HNO3, 3-methylcyclohexanone and 4-methylcyclohexanone gave comparable results to cyclohexanone. However, alkyl substitution of cyclohexanone significantly slows down the extraction kinetics compared to cyclohexanone, and the position of alkyl substitution was found to play an important role in the solvents properties. 3-Methylcyclohexanone was identified as the most promising of the diluents. (en)
Title	Influence of diluent alkyl substituion on the extraction of Am(III) and Eu(III) by a 6,6'-bis(1,2,4-triazin-3-yl)-2,2'-bipyridine ligand dissolved in alkylated cyclohexanone diluents Influence of diluent alkyl substituion on the extraction of Am(III) and Eu(III) by a 6,6'-bis(1,2,4-triazin-3-yl)-2,2'-bipyridine ligand dissolved in alkylated cyclohexanone diluents (en)
skos:prefLabel	Influence of diluent alkyl substituion on the extraction of Am(III) and Eu(III) by a 6,6'-bis(1,2,4-triazin-3-yl)-2,2'-bipyridine ligand dissolved in alkylated cyclohexanone diluents Influence of diluent alkyl substituion on the extraction of Am(III) and Eu(III) by a 6,6'-bis(1,2,4-triazin-3-yl)-2,2'-bipyridine ligand dissolved in alkylated cyclohexanone diluents (en)
skos:notation	RIV/68407700:21340/12:00205642!RIV14-MSM-21340___
http://linked.open...avai/predkladatel	Fakulta jaderná a fyzikálně inženýrská
http://linked.open...avai/riv/aktivita	R
http://linked.open...avai/riv/aktivity	R
http://linked.open...iv/cisloPeriodika	100
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	John, Jan Špendlíková, Irena Distler, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	České vysoké učení technické v Praze / Fakulta jaderná a fyzikálně inženýrská
http://linked.open...dnocenehoVysledku	141397
http://linked.open...ai/riv/idVysledku	RIV/68407700:21340/12:00205642
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	cyclohexanone; solvent extraction; minor actinoids; cyclohexanone derivatives (en)
http://linked.open.../riv/klicoveSlovo	solvent extraction cyclohexanone cyclohexanone derivatives minor actinoids
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[9EDD207D4802]
http://linked.open...i/riv/nazevZdroje	Radiochimica Acta
http://linked.open...in/vavai/riv/obor	CH
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	2012 (10)
http://linked.open...iv/tvurceVysledku	John, Jan Špendlíková, Irena Distler, Petr Harwood, L. M. Hudson, M. J. Lewis, F. W.
http://linked.open...ain/vavai/riv/wos	000316063800002
issn	0033-8230
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1524/ract.2012.1949
http://localhost/t...ganizacniJednotka	21340

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