About: Use of the Free-Liquid Electrophoresis for the Analysis of Thorium Complexation with Humic Acid at Low pH Values     Goto   Sponge   NotDistinct   Permalink

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  • Abundances of humate complexes of thorium and the mean electrophoretic mobilities of the complexes, at pH 2-4 in solutions of 0.01M (HClO4 + NaClO4) containing Aldrich humic acid (HA), were calculated from the electrophoretic mobilities of 234Th towards cathode and anode, respectively. The abundances higher than 90% were found except for cases when the loading of HA with thorium was close to the saturation of binding capacity of HA. The mobilities of ThHA complexes only towards anode were observed, i.e. no positively charged complexes were formed.
  • Abundances of humate complexes of thorium and the mean electrophoretic mobilities of the complexes, at pH 2-4 in solutions of 0.01M (HClO4 + NaClO4) containing Aldrich humic acid (HA), were calculated from the electrophoretic mobilities of 234Th towards cathode and anode, respectively. The abundances higher than 90% were found except for cases when the loading of HA with thorium was close to the saturation of binding capacity of HA. The mobilities of ThHA complexes only towards anode were observed, i.e. no positively charged complexes were formed. (en)
  • Na základě poklesu elektroforetické pohyblivosti 234Th ke katodě přídavkem huminové kyseliny Aldrich (HA) bylo vypočteno zastoupení komplexů ThHA a z pohyblivosti 234Th k anodě byla stanovena střední pohyblivost těchto komplexů v roztocích 0.01M (HClO4 + NaClO4) o pH 2-4. Bylo zjištěno, že toto zastoupení je větší než 90% s výjimkou případů, kdy obsazení HA thoriem se blíží nasycení komplexační kapacity HA. Ve všech případech komplexy ThHA migrovaly pouze k anodě, tj. nebyl pozorován vznik kladně nabitých komplexů. (cs)
Title
  • Use of the Free-Liquid Electrophoresis for the Analysis of Thorium Complexation with Humic Acid at Low pH Values
  • Použití elektroforézy ve volné kapalině pro analýzu komplexace thoria s huminovou kyselinou při nízkých hodnotách pH (cs)
  • Use of the Free-Liquid Electrophoresis for the Analysis of Thorium Complexation with Humic Acid at Low pH Values (en)
skos:prefLabel
  • Use of the Free-Liquid Electrophoresis for the Analysis of Thorium Complexation with Humic Acid at Low pH Values
  • Použití elektroforézy ve volné kapalině pro analýzu komplexace thoria s huminovou kyselinou při nízkých hodnotách pH (cs)
  • Use of the Free-Liquid Electrophoresis for the Analysis of Thorium Complexation with Humic Acid at Low pH Values (en)
skos:notation
  • RIV/68407700:21340/05:04112318!RIV06-MSM-21340___
http://linked.open.../vavai/riv/strany
  • 736 ; 737
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  • Z(MSM 210000019)
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  • 548113
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  • RIV/68407700:21340/05:04112318
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  • Th 234; aqueous solutions; electrophoresis; humic complexes; speciation; thorium (en)
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  • [5BCF0959A179]
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  • Praha
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  • Praha
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  • Proceedings of Workshop 2005 - Part A,B
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  • Beneš, Petr
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number of pages
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  • České vysoké učení technické v Praze
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  • 80-01-03201-9
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  • 21340
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