About: New chiral liquid crystal with unconventional dioxane terminal unit

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Whereas designing new chiral self-assembling materials i.e. those possessing the liquid crystalline behaviour, special attention should be paid to the specific architecture of different molecular parts, in particular molecular core, linkage groups, type and place of the lateral substituents, structure of the chiral centre and the chiral and non-chiral chains. For the first time a new chiral photosensitive liquid crystalline compound possessing an unconventional pentaglyform terminal unit attached to the non-chiral chain has been designed and synthesised. On cooling from the isotropic phase the material possesses two tilted phases: an ordinary smectic C* phase and smectic I* phase with hexagonal ordering. The self-assembling and structural behaviour have been studied by different techniques and compared to that of the materials with similar molecular structure but possessing structurally different terminal units in the non-chiral chain. Whereas designing new chiral self-assembling materials i.e. those possessing the liquid crystalline behaviour, special attention should be paid to the specific architecture of different molecular parts, in particular molecular core, linkage groups, type and place of the lateral substituents, structure of the chiral centre and the chiral and non-chiral chains. For the first time a new chiral photosensitive liquid crystalline compound possessing an unconventional pentaglyform terminal unit attached to the non-chiral chain has been designed and synthesised. On cooling from the isotropic phase the material possesses two tilted phases: an ordinary smectic C* phase and smectic I* phase with hexagonal ordering. The self-assembling and structural behaviour have been studied by different techniques and compared to that of the materials with similar molecular structure but possessing structurally different terminal units in the non-chiral chain. (en)
Title	New chiral liquid crystal with unconventional dioxane terminal unit New chiral liquid crystal with unconventional dioxane terminal unit (en)
skos:prefLabel	New chiral liquid crystal with unconventional dioxane terminal unit New chiral liquid crystal with unconventional dioxane terminal unit (en)
skos:notation	RIV/68378271:_____/14:00436876!RIV15-GA0-68378271
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(7AMB13PL041), P(7AMB14PL035), P(GA13-14133S), P(LD14007)
http://linked.open...iv/cisloPeriodika	10-11
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Bubnov, Alexej Kašpar, Miroslav Hamplová, Věra
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Fyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	32349
http://linked.open...ai/riv/idVysledku	RIV/68378271:_____/14:00436876
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	chiral liquid crysta; pentaglyform unit; structural properties; smectic phase; hexagonal ordering; self-assembling (en)
http://linked.open.../riv/klicoveSlovo	structural properties self-assembling smectic phase chiral liquid crysta hexagonal ordering pentaglyform unit
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[DE543FBF58C1]
http://linked.open...i/riv/nazevZdroje	Phase Transitions
http://linked.open...in/vavai/riv/obor	JJ
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Nanokompozitní systémy tvořené kapalně krystalickými molekulami a nanočásticemi Multifunkční kapalně krystalické látky a hybridní nanokompozitní systémy Challenging chiral self-assembling materials for photonic applications: structures and properties Perspektivní funkční materiály s polárním uspořádáním v nano měřítku
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	87
http://linked.open...iv/tvurceVysledku	Bubnov, Alexej Hamplová, Věra Kašpar, Miroslav Pociecha, D. Perkowski, P. Piecek, W. Mrukiewicz, M.
http://linked.open...ain/vavai/riv/wos	000345840100014
issn	0141-1594
number of pages	14 (xsd:int)
http://bibframe.org/vocab/doi	10.1080/01411594.2014.953515

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