About: Synthesis, characterization, thermogravimetry, and structural study of uranium complexes derived from dibasic S-alkylated thiosemicarbazone ligands     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • Two pentagonal bipyramidal complexes, ethanol-(S-ethyl-N1,N4-bis(3-methoxy-2-hydroxybenzaldehyde)-isothiosemicarbazide-N,N’,O,O’)-dioxidouranium(VI) (1) and ethanol-(S-ethyl-N1-(2-hydroxyacetophenone)-N4-(5-bromo-2-hydroxybenzaldehyde)-isothiosemicarbazide-N,N’,O,O’)-dioxidouranium(VI) (2), have been prepared and characterized. Their structures have been determined by X-ray crystallography, and the structural parameters are discussed with those observed in related complexes. Electronic absorption, proton magnetic resonance, and FT-IR spectra have been recorded and analyzed. In both comple xes, the U(VI) centers are surrounded by N2O2 donor ligands, two oxido groups, and one ethanol in a distorted pentagonal bipyramid. The thermal stability of the new complexes has also been determined.
  • Two pentagonal bipyramidal complexes, ethanol-(S-ethyl-N1,N4-bis(3-methoxy-2-hydroxybenzaldehyde)-isothiosemicarbazide-N,N’,O,O’)-dioxidouranium(VI) (1) and ethanol-(S-ethyl-N1-(2-hydroxyacetophenone)-N4-(5-bromo-2-hydroxybenzaldehyde)-isothiosemicarbazide-N,N’,O,O’)-dioxidouranium(VI) (2), have been prepared and characterized. Their structures have been determined by X-ray crystallography, and the structural parameters are discussed with those observed in related complexes. Electronic absorption, proton magnetic resonance, and FT-IR spectra have been recorded and analyzed. In both comple xes, the U(VI) centers are surrounded by N2O2 donor ligands, two oxido groups, and one ethanol in a distorted pentagonal bipyramid. The thermal stability of the new complexes has also been determined. (en)
Title
  • Synthesis, characterization, thermogravimetry, and structural study of uranium complexes derived from dibasic S-alkylated thiosemicarbazone ligands
  • Synthesis, characterization, thermogravimetry, and structural study of uranium complexes derived from dibasic S-alkylated thiosemicarbazone ligands (en)
skos:prefLabel
  • Synthesis, characterization, thermogravimetry, and structural study of uranium complexes derived from dibasic S-alkylated thiosemicarbazone ligands
  • Synthesis, characterization, thermogravimetry, and structural study of uranium complexes derived from dibasic S-alkylated thiosemicarbazone ligands (en)
skos:notation
  • RIV/68378271:_____/14:00434948!RIV15-GA0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GA14-03276S)
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 49010
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/14:00434948
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • uranium complex; isothiosemicarbazone; crystallography; spectra; thermal stability (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [50154245DE5C]
http://linked.open...i/riv/nazevZdroje
  • Journal of Coordination Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 67
http://linked.open...iv/tvurceVysledku
  • Dušek, Michal
  • Pojarová, Michaela
  • Ahmadi, M.
  • Barak, T.
  • Fasihizad, A.
http://linked.open...ain/vavai/riv/wos
  • 000340154000010
issn
  • 0095-8972
number of pages
http://bibframe.org/vocab/doi
  • 10.1080/00958972.2014.936860
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software