About: On the origin of cerium-related centres in lead-containing single crystalline films of Y2SiO5:Ce and Lu2SiO5:Ce     Goto   Sponge   NotDistinct   Permalink

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  • Absorption, electron spin resonance, and photo- and thermally stimulated luminescence characteristics are studied for single crystalline films (SCFs) of Y2SiO5 :Ce and Lu2SiO5 : Ce prepared by the liquid phase epitaxy method with the use of a PbO-containing flux. It is suggested that stable tetravalent Ce4+ ions mainly exist in the SCF due to a large concentration of Pb2+ ions whose excess volume and negative charge can be effectively compensated by relatively small tetravalent Ce4+ ions. Nevertheless, the characteristic Ce3+ emission in the SCFs of Y2SiO5 :Ce and Lu2SiO5 :Ce does appear under photoexcitation in the charge-transfer absorption region (Eexc > 4.2 eV), most probably as a result of the two-photon excitation process.
  • Absorption, electron spin resonance, and photo- and thermally stimulated luminescence characteristics are studied for single crystalline films (SCFs) of Y2SiO5 :Ce and Lu2SiO5 : Ce prepared by the liquid phase epitaxy method with the use of a PbO-containing flux. It is suggested that stable tetravalent Ce4+ ions mainly exist in the SCF due to a large concentration of Pb2+ ions whose excess volume and negative charge can be effectively compensated by relatively small tetravalent Ce4+ ions. Nevertheless, the characteristic Ce3+ emission in the SCFs of Y2SiO5 :Ce and Lu2SiO5 :Ce does appear under photoexcitation in the charge-transfer absorption region (Eexc > 4.2 eV), most probably as a result of the two-photon excitation process. (en)
Title
  • On the origin of cerium-related centres in lead-containing single crystalline films of Y2SiO5:Ce and Lu2SiO5:Ce
  • On the origin of cerium-related centres in lead-containing single crystalline films of Y2SiO5:Ce and Lu2SiO5:Ce (en)
skos:prefLabel
  • On the origin of cerium-related centres in lead-containing single crystalline films of Y2SiO5:Ce and Lu2SiO5:Ce
  • On the origin of cerium-related centres in lead-containing single crystalline films of Y2SiO5:Ce and Lu2SiO5:Ce (en)
skos:notation
  • RIV/68378271:_____/14:00432354!RIV15-GA0-68378271
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  • I, P(GAP204/12/0805)
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  • 6
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  • 34484
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  • RIV/68378271:_____/14:00432354
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  • luminescence; Lu2SiO5:Ce; scintillators (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [DFF9853A732C]
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  • Journal of Physics D-Applied Physics
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  • 47
http://linked.open...iv/tvurceVysledku
  • Nikl, Martin
  • Laguta, Valentyn
  • Zazubovich, S.
  • Kärner, T.
  • Shalapska, T.
http://linked.open...ain/vavai/riv/wos
  • 000331468100021
issn
  • 0022-3727
number of pages
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  • 10.1088/0022-3727/47/6/065303
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