About: Molecular tilt near nanoparticles in the smectic A phase of de Vries liquid-crystalline compound     Goto   Sponge   NotDistinct   Permalink

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  • We show how the inclusions of the nanoparticles or the clusters of nanoparticles in the liquid crystalline smectic A phase lead to the layer deformations and may create a tilt in their vicinity, thus inducing locally a smectic A-smectic C transition. We have studied a free-standing film of “de Vries compound, which exhibits the smectic A-smectic C transition without layer shrinkage, mixed with functionalized gold-nanoparticles. For the first time the tilt induced by nanoparticle clusters, which decorate the edge dislocations, has been observed in the smectic A phase. In this case the tilt of liquid crystal molecules near nanoparticles is a consequence of interaction of liquid crystalline molecules with the surface of nanoparticle. The observed tilt may prove the concept of existence of a disordered tilt in the smectic A phase of “de Vries compounds. The tilt distribution near nanoparticles is discussed.
  • We show how the inclusions of the nanoparticles or the clusters of nanoparticles in the liquid crystalline smectic A phase lead to the layer deformations and may create a tilt in their vicinity, thus inducing locally a smectic A-smectic C transition. We have studied a free-standing film of “de Vries compound, which exhibits the smectic A-smectic C transition without layer shrinkage, mixed with functionalized gold-nanoparticles. For the first time the tilt induced by nanoparticle clusters, which decorate the edge dislocations, has been observed in the smectic A phase. In this case the tilt of liquid crystal molecules near nanoparticles is a consequence of interaction of liquid crystalline molecules with the surface of nanoparticle. The observed tilt may prove the concept of existence of a disordered tilt in the smectic A phase of “de Vries compounds. The tilt distribution near nanoparticles is discussed. (en)
Title
  • Molecular tilt near nanoparticles in the smectic A phase of de Vries liquid-crystalline compound
  • Molecular tilt near nanoparticles in the smectic A phase of de Vries liquid-crystalline compound (en)
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  • Molecular tilt near nanoparticles in the smectic A phase of de Vries liquid-crystalline compound
  • Molecular tilt near nanoparticles in the smectic A phase of de Vries liquid-crystalline compound (en)
skos:notation
  • RIV/68378271:_____/14:00427097!RIV15-GA0-68378271
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  • I, P(GAP204/11/0723)
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  • 1
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  • 30309
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  • RIV/68378271:_____/14:00427097
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  • liquid crystals; smectic phases; nanoparticles; deVries behaviour (en)
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  • US - Spojené státy americké
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  • [6CA1B59E9756]
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  • Physical Review. E
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  • 89
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  • Glogarová, Milada
  • Novotná, Vladimíra
  • Lejček, Lubor
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  • 000332166500005
issn
  • 1539-3755
number of pages
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  • 10.1103/PhysRevE.89.012505
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