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  • The phase purity and the lattice dynamics in bulk EuTiO3 were investigated both microscopically, using x-ray and neutron diffraction, 151 Eu-Mössbauer spectroscopy, and 151 Eu nuclear inelastic scattering, and macroscopically using calorimetry, resonant ultrasound spectroscopy, and magnetometry. A stiffening on heating around room temperature is indicative of a phase transition similar to the one observed in SrTiO3, however, although previous studies reported the structural phase transition to the tetragonal I4/mcm phase our detailed sample purity analysis and thorough structural studies using comple mentary techniques did not confirm a direct phase transition. Instead, in the same temperature range, Eu delocalization is observed which might explain the lattice dynamical instabilities.
  • The phase purity and the lattice dynamics in bulk EuTiO3 were investigated both microscopically, using x-ray and neutron diffraction, 151 Eu-Mössbauer spectroscopy, and 151 Eu nuclear inelastic scattering, and macroscopically using calorimetry, resonant ultrasound spectroscopy, and magnetometry. A stiffening on heating around room temperature is indicative of a phase transition similar to the one observed in SrTiO3, however, although previous studies reported the structural phase transition to the tetragonal I4/mcm phase our detailed sample purity analysis and thorough structural studies using comple mentary techniques did not confirm a direct phase transition. Instead, in the same temperature range, Eu delocalization is observed which might explain the lattice dynamical instabilities. (en)
Title
  • Lattice instabilities in bulk EuTiO3.
  • Lattice instabilities in bulk EuTiO3. (en)
skos:prefLabel
  • Lattice instabilities in bulk EuTiO3.
  • Lattice instabilities in bulk EuTiO3. (en)
skos:notation
  • RIV/68378271:_____/13:00399505!RIV14-MSM-68378271
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  • I, P(ED1.1.00/02.0068), P(GAP204/12/1163), P(LD11035), P(LD12026)
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  • 14
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  • RIV/68378271:_____/13:00399505
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  • structural phase transition; phonons; lattice dynamics (en)
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  • US - Spojené státy americké
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  • [4D195430226E]
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  • Physical Review. B
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  • 88
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  • Kamba, Stanislav
  • Máca, K.
  • Ležaič, M.
  • Rushchanskii, K. Z.
  • Kachlik, M.
  • Gourdon, O.
  • Bednarcik, J.
  • Bessas, D.
  • Disch, S.
  • Hermann, R. P.
  • Sergueev, I.
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  • 000326159200002
issn
  • 1098-0121
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  • 10.1103/PhysRevB.88.144308
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