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  • Linear antenna microwave chemical vapor deposition process was used to homogeneously coat a 7 cm long silicon prism by 85 nm thin nanocrystalline diamond (NCD) layer. To show the advantages of the NCD-coated prism for attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) of nanoparticles, we apply diamond nanoparticles (DNPs) of 5 nm nominal size with various surface modifications by a drop-casting of their methanol dispersions. ATR-FTIR spectra of as-received, air-annealed, plasma-oxidized, and plasma-hydrogenated DNPs were measured in the 4000-1500 cm-1 spectral range. The spectra show high spectral resolution, high sensitivity to specific DNP surface moieties, and repeatability. The NCD coating provides mechanical protection against scratching and chemical stability of the surface.
  • Linear antenna microwave chemical vapor deposition process was used to homogeneously coat a 7 cm long silicon prism by 85 nm thin nanocrystalline diamond (NCD) layer. To show the advantages of the NCD-coated prism for attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) of nanoparticles, we apply diamond nanoparticles (DNPs) of 5 nm nominal size with various surface modifications by a drop-casting of their methanol dispersions. ATR-FTIR spectra of as-received, air-annealed, plasma-oxidized, and plasma-hydrogenated DNPs were measured in the 4000-1500 cm-1 spectral range. The spectra show high spectral resolution, high sensitivity to specific DNP surface moieties, and repeatability. The NCD coating provides mechanical protection against scratching and chemical stability of the surface. (en)
Title
  • Diamond-coated ATR prism for infrared absorption spectroscopy of surface-modified diamond nanoparticles
  • Diamond-coated ATR prism for infrared absorption spectroscopy of surface-modified diamond nanoparticles (en)
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  • Diamond-coated ATR prism for infrared absorption spectroscopy of surface-modified diamond nanoparticles
  • Diamond-coated ATR prism for infrared absorption spectroscopy of surface-modified diamond nanoparticles (en)
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  • RIV/68378271:_____/13:00399386!RIV14-MSM-68378271
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  • I, P(GAP108/12/0910), P(GPP205/12/P331), P(LH12186), P(LH12236), S
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  • 69413
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  • RIV/68378271:_____/13:00399386
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  • ATR FTIR; CVD; hydrogenation; microwave; nanocrystalline diamond; nanopowder (en)
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  • NL - Nizozemsko
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  • [18953295A7E5]
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  • Applied Surface Science
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  • 270
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  • Babchenko, Oleg
  • Kromka, Alexander
  • Rezek, Bohuslav
  • Ukraintsev, Egor
  • Remeš, Zdeněk
  • Kozak, Halyna
  • Bergonzo, P.
  • Arnault, J.-C.
  • Girard, H. A.
http://linked.open...ain/vavai/riv/wos
  • 000316790200062
issn
  • 0169-4332
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.apsusc.2013.01.039
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