About: Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of γ-Fe2O3 nanoparticles     Goto   Sponge   NotDistinct   Permalink

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  • Hydrophobic (oleic acid) coating effect on the magnetic properties of maghemite(γ-Fe2O3) nanoparticles investigated. Particles prepared by a novel bi-phasic co-precipitation way and their properties compared with uncoated particles and particles prepared by a standard single-phase way. Oleic acid coated particles had a mean diameter of 6nm when the two-phase precipitation procedure was used, compared to 12nm-nanoparticles prepared in a single phase under otherwise identical conditions. Super Quantum Interference Device measurements show superparamagnetism of the nanoparticles, with a saturation magnetization at 4K to be 66.4 emu/g and 89.0 emu/g for the coated nanoparticles obtained by two-and single-phase procedure, respectively. ZFC and FC curves reveal a dramatic shift in the blocking temp.of the coated particles,and a significant change in their anisotropy.Hydrophobic nanoparticles were able to form stable ferrofluids in a range of organic solvents and show good heating rates in a 400kHz alternating magnetic field.
  • Hydrophobic (oleic acid) coating effect on the magnetic properties of maghemite(γ-Fe2O3) nanoparticles investigated. Particles prepared by a novel bi-phasic co-precipitation way and their properties compared with uncoated particles and particles prepared by a standard single-phase way. Oleic acid coated particles had a mean diameter of 6nm when the two-phase precipitation procedure was used, compared to 12nm-nanoparticles prepared in a single phase under otherwise identical conditions. Super Quantum Interference Device measurements show superparamagnetism of the nanoparticles, with a saturation magnetization at 4K to be 66.4 emu/g and 89.0 emu/g for the coated nanoparticles obtained by two-and single-phase procedure, respectively. ZFC and FC curves reveal a dramatic shift in the blocking temp.of the coated particles,and a significant change in their anisotropy.Hydrophobic nanoparticles were able to form stable ferrofluids in a range of organic solvents and show good heating rates in a 400kHz alternating magnetic field. (en)
Title
  • Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of γ-Fe2O3 nanoparticles
  • Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of γ-Fe2O3 nanoparticles (en)
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  • Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of γ-Fe2O3 nanoparticles
  • Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of γ-Fe2O3 nanoparticles (en)
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  • RIV/68378271:_____/13:00397844!RIV14-AV0-68378271
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  • RIV/68378271:_____/13:00397844
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  • nanoparticle; maghemite; blocking temperature; superparamagnetism; saturation magnetization (en)
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  • Journal of Magnetism and Magnetic Materials
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  • 339
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  • Svoboda, P.
  • Šantavá, Eva
  • Singh, M.
  • Ulbrich, P.
  • Štěpánek, F.
  • Prokopec, V.
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  • 000318904100019
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  • 0304-8853
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  • 10.1016/j.jmmm.2013.02.051
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