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  • Two new binuclear complexes were synthesized by a hydrothermal process and characterized by elemental analysis, IR spectroscopy, thermal analysis, and X-ray single crystal diffraction. Both compounds contain two Hamp cations and a dinuclear manganese(II) or vanadium(V) anion complex. Two manganese(II) ions are bridged by pyridine-2,6-dicarboxylate ions in the manganese complex,and they are both coordinated in a distorted pentagonal-bipyramidal geometry. Vanadium(V) ions are coordinated octahedrally. The crystal structures of both complexes are stabilized by a complex network of hydrogen bonds.
  • Two new binuclear complexes were synthesized by a hydrothermal process and characterized by elemental analysis, IR spectroscopy, thermal analysis, and X-ray single crystal diffraction. Both compounds contain two Hamp cations and a dinuclear manganese(II) or vanadium(V) anion complex. Two manganese(II) ions are bridged by pyridine-2,6-dicarboxylate ions in the manganese complex,and they are both coordinated in a distorted pentagonal-bipyramidal geometry. Vanadium(V) ions are coordinated octahedrally. The crystal structures of both complexes are stabilized by a complex network of hydrogen bonds. (en)
Title
  • Synthesis, crystal structure, and spectroscopic characterization of two new binuclear complexes of manganese(II) and vanadium(V) with dipicolinate ligands containing 2-aminopyrimidinium as a counter cation
  • Synthesis, crystal structure, and spectroscopic characterization of two new binuclear complexes of manganese(II) and vanadium(V) with dipicolinate ligands containing 2-aminopyrimidinium as a counter cation (en)
skos:prefLabel
  • Synthesis, crystal structure, and spectroscopic characterization of two new binuclear complexes of manganese(II) and vanadium(V) with dipicolinate ligands containing 2-aminopyrimidinium as a counter cation
  • Synthesis, crystal structure, and spectroscopic characterization of two new binuclear complexes of manganese(II) and vanadium(V) with dipicolinate ligands containing 2-aminopyrimidinium as a counter cation (en)
skos:notation
  • RIV/68378271:_____/13:00397463!RIV14-GA0-68378271
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  • I, P(GAP204/11/0809)
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  • 5
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  • 109507
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  • RIV/68378271:_____/13:00397463
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  • manganese complex; vanadium complex; dipicolinic ligand; crystal structure (en)
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  • AT - Rakouská republika
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  • [ECCEC9F66007]
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  • Monatshefte fur Chemie
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  • 144
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  • Dušek, Michal
  • Pojarová, Michaela
  • Tabatabaee, M.
  • Ahadiat, G.
  • Mahmoodikhah, H.
http://linked.open...ain/vavai/riv/wos
  • 000317713800006
issn
  • 0026-9247
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s00706-012-0878-2
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