About: Defect structure of nanosized zirconium oxide powders doped with Y2O3, Sc2O3, Cr2O3.     Goto   Sponge   NotDistinct   Permalink

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  • The formation mechanisms of paramagnetic centers originating from Zr3+ and Cr5+ ions and the influence of the nanoparticle composition on thermal generation processes of these paramagnetic centers were studied in ZrO2 structure by electron paramagnetic resonance. A set of nanosized zirconium oxide powders ( nominally pure ZrO2, ZrO2 doped with correspondingly Y2O3 and Sc2O3, Cr2O3 and Y2O3, as well as Cr2O3 ) was investigated. Annealing effects on the EPR lines of Zr3+ and Cr5+ ions were found to be different. Annealing curves of EPR signals caused by Cr5+ ions have a maximum in temperature range 500–600 oC. Mechanisms of Zr3+ and Cr5+ ions formation were discussed.
  • The formation mechanisms of paramagnetic centers originating from Zr3+ and Cr5+ ions and the influence of the nanoparticle composition on thermal generation processes of these paramagnetic centers were studied in ZrO2 structure by electron paramagnetic resonance. A set of nanosized zirconium oxide powders ( nominally pure ZrO2, ZrO2 doped with correspondingly Y2O3 and Sc2O3, Cr2O3 and Y2O3, as well as Cr2O3 ) was investigated. Annealing effects on the EPR lines of Zr3+ and Cr5+ ions were found to be different. Annealing curves of EPR signals caused by Cr5+ ions have a maximum in temperature range 500–600 oC. Mechanisms of Zr3+ and Cr5+ ions formation were discussed. (en)
Title
  • Defect structure of nanosized zirconium oxide powders doped with Y2O3, Sc2O3, Cr2O3.
  • Defect structure of nanosized zirconium oxide powders doped with Y2O3, Sc2O3, Cr2O3. (en)
skos:prefLabel
  • Defect structure of nanosized zirconium oxide powders doped with Y2O3, Sc2O3, Cr2O3.
  • Defect structure of nanosized zirconium oxide powders doped with Y2O3, Sc2O3, Cr2O3. (en)
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  • RIV/68378271:_____/13:00394500!RIV14-AV0-68378271
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  • 68143
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  • RIV/68378271:_____/13:00394500
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  • nanosized powder; defects; dopant; electron paramagnetic resonance (en)
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  • [6A96E270A1D4]
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  • Lviv
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  • Zurich
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  • Oxide materials for electronic engineering - fabrication, properties and applications
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  • Dejneka, Alexandr
  • Jastrabík, Lubomír
  • Suchaneck, G.
  • Yurchenko, L. P.
  • Brik, A. B.
  • Bykov, I. P.
  • Vasylyev, O. D.
  • Vereshchak, V. G.
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  • 000319786500018
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  • 1012-0394
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  • 10.4028/www.scientific.net/SSP.200.108
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  • Trans tech publications Ltd.
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