About: Thermodynamic study of selected monoterpenes

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A thermodynamic study of important biogenic compounds, (–)-α-pinene, (–)-β-pinene, (–)-cis-verbenol, and (–)-verbenone, is presented in this work. The vapor pressure measurements were performed using the static method over the environmentally important temperature range from 238 to 313 K. The sublimation and vaporization enthalpies were derived from these measurements as well as directly determined by a Calvet high temperature microcalorimeter. Heat capacities of condensed phases were measured by Calvet and drop calorimetry in the temperature interval from 273 to 355 K. The thermodynamic properties of the ideal-gas state were calculated by combining statistical thermodynamics and density functional theory (DFT) calculations. The trends in thermodynamic properties within the group of compounds possessing similar molecular structures are discussed. A thermodynamic study of important biogenic compounds, (–)-α-pinene, (–)-β-pinene, (–)-cis-verbenol, and (–)-verbenone, is presented in this work. The vapor pressure measurements were performed using the static method over the environmentally important temperature range from 238 to 313 K. The sublimation and vaporization enthalpies were derived from these measurements as well as directly determined by a Calvet high temperature microcalorimeter. Heat capacities of condensed phases were measured by Calvet and drop calorimetry in the temperature interval from 273 to 355 K. The thermodynamic properties of the ideal-gas state were calculated by combining statistical thermodynamics and density functional theory (DFT) calculations. The trends in thermodynamic properties within the group of compounds possessing similar molecular structures are discussed. (en)
Title	Thermodynamic study of selected monoterpenes Thermodynamic study of selected monoterpenes (en)
skos:prefLabel	Thermodynamic study of selected monoterpenes Thermodynamic study of selected monoterpenes (en)
skos:notation	RIV/68378271:_____/13:00391739!RIV14-AV0-68378271
http://linked.open...avai/predkladatel	Fyzikální ústav AV ČR, v.v.i.
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(ME10049)
http://linked.open...iv/cisloPeriodika	MAY
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Fulem, Michal
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Fyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	110949
http://linked.open...ai/riv/idVysledku	RIV/68378271:_____/13:00391739
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	monoterpenes; pinene; vapor pressure; heat capacity; vaporization and sublimation enthalpy; ideal-gas thermodynamic (en)
http://linked.open.../riv/klicoveSlovo	vapor pressure monoterpenes ideal-gas thermodynamic pinene vaporization and sublimation enthalpy heat capacity
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[364595A29FDC]
http://linked.open...i/riv/nazevZdroje	Journal of Chemical Thermodynamics
http://linked.open...in/vavai/riv/obor	BJ
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Reliable vapor pressure measurements for electronics and optical coatings
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	60
http://linked.open...iv/tvurceVysledku	Fulem, Michal Růžička, K. Rocha, M. A. A. Santos, L.M.N.B.F. Červinka, C. Schröder, B. Štejfa, V.
http://linked.open...ain/vavai/riv/wos	000315681200018
issn	0021-9614
number of pages	9 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jct.2013.01.009

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