About: Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub

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About: Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Calciodelrioite, ideally Ca(VO3)2(H2O)4, is a new mineral (IMA 2012-031). It is monoclinic, I2/a, with a=14.6389(10), b=6.9591(4), c=17.052(2) A , beta=102.568(9)°, V=1695.5(3) A3 and Z=8. In the structure of calciodelrioite (refined to R1=3.14% for 1216 Fo>4δF),V5+O5 polyhedra link by sharing edges to form a zigzag divanadate [VO3] chain along a, similar to that in the structure of rossite. The chains are linked via bonds to Ca atoms, which also bond to H2O groups, yielding CaO3(H2O)6 polyhedra. The Ca polyhedra form a chain along b. Each of the two symmetrically independent VO5 polyhedra has two short vanadyl bonds and three long equatorial bonds. Calciodelrioite and delrioite are isostructural and are the endmembers of the series Ca-Sr. Calciodelrioite is dimorphous with rossite, which has a similar structure; however, the smaller 8-coordinate Ca site in rossite does not accommodate Sr. Calciodelrioite, ideally Ca(VO3)2(H2O)4, is a new mineral (IMA 2012-031). It is monoclinic, I2/a, with a=14.6389(10), b=6.9591(4), c=17.052(2) A , beta=102.568(9)°, V=1695.5(3) A3 and Z=8. In the structure of calciodelrioite (refined to R1=3.14% for 1216 Fo>4δF),V5+O5 polyhedra link by sharing edges to form a zigzag divanadate [VO3] chain along a, similar to that in the structure of rossite. The chains are linked via bonds to Ca atoms, which also bond to H2O groups, yielding CaO3(H2O)6 polyhedra. The Ca polyhedra form a chain along b. Each of the two symmetrically independent VO5 polyhedra has two short vanadyl bonds and three long equatorial bonds. Calciodelrioite and delrioite are isostructural and are the endmembers of the series Ca-Sr. Calciodelrioite is dimorphous with rossite, which has a similar structure; however, the smaller 8-coordinate Ca site in rossite does not accommodate Sr. (en)
Title	Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub (en)
skos:prefLabel	Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub (en)
skos:notation	RIV/68378271:_____/12:00389446!RIV13-AV0-68378271
http://linked.open...avai/predkladatel	Fyzikální ústav AV ČR, v.v.i.
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z10100521)
http://linked.open...iv/cisloPeriodika	7
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Plášil, Jakub
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Fyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	125793
http://linked.open...ai/riv/idVysledku	RIV/68378271:_____/12:00389446
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	calciodelrioite; new mineral; crystal structure; divanadate chain; delrioite; rossite; West Sunday mine, Colorado (en)
http://linked.open.../riv/klicoveSlovo	Colorado West Sunday mine calciodelrioite delrioite divanadate chain rossite crystal structure new mineral
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[A0D615543AB8]
http://linked.open...i/riv/nazevZdroje	Mineralogical Magazine
http://linked.open...in/vavai/riv/obor	BM
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	76
http://linked.open...iv/tvurceVysledku	Kampf, A. R. Plášil, Jakub Škoda, R. Kasatkin, A. V. Marty, J. Nash, B. P.
http://linked.open...n/vavai/riv/zamer	Physics and technology of nanostructures, surfaces and thin films
issn	0026-461X
number of pages	15 (xsd:int)
http://bibframe.org/vocab/doi	10.1180/minmag.2012.076.7.12
is http://linked.open...avai/riv/vysledek of	Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub

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