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  • Electrostatic charging of oxygen-terminated nanocrystalline diamond (NCD) thin films deposited on silicon in sub-100 nm thickness and with intentionally high relative sp2 phase ratio (60%) is characterized on a microscopic level. By correlating Kelvin Force Microscopy, Current-Sensing Atomic Force Microscopy, micro-Raman spectroscopy and cross-sectional Scanning Electron Microscopy data we show that the charging is determined by both the surface topography (grains and grain boundaries) and complex sub-surface morphology (arrangement of grains and sp2 phase) on scales below 2 2 um2. These microscopic data and macroscopic I(V) characteristics evidence that sp2 phase dominates over diamond grains in local electrostatic charging of NCD thin films. Moreover, the tip-surface junction quality is identified as the main factor behind large variations (0.1 to 1 V) of the overall induced electrostatic charge contrast.
  • Electrostatic charging of oxygen-terminated nanocrystalline diamond (NCD) thin films deposited on silicon in sub-100 nm thickness and with intentionally high relative sp2 phase ratio (60%) is characterized on a microscopic level. By correlating Kelvin Force Microscopy, Current-Sensing Atomic Force Microscopy, micro-Raman spectroscopy and cross-sectional Scanning Electron Microscopy data we show that the charging is determined by both the surface topography (grains and grain boundaries) and complex sub-surface morphology (arrangement of grains and sp2 phase) on scales below 2 2 um2. These microscopic data and macroscopic I(V) characteristics evidence that sp2 phase dominates over diamond grains in local electrostatic charging of NCD thin films. Moreover, the tip-surface junction quality is identified as the main factor behind large variations (0.1 to 1 V) of the overall induced electrostatic charge contrast. (en)
Title
  • How nanocrystalline diamond films become charged in nanoscale
  • How nanocrystalline diamond films become charged in nanoscale (en)
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  • How nanocrystalline diamond films become charged in nanoscale
  • How nanocrystalline diamond films become charged in nanoscale (en)
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  • RIV/68378271:_____/12:00386473!RIV13-GA0-68378271
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  • P(GAP204/10/0212), P(GD202/09/H041), P(KAN400100701), P(LC06040), P(LC510), Z(AV0Z10100521)
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  • 4
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  • 139685
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  • RIV/68378271:_____/12:00386473
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  • nanocrystalline diamond; local electrostatic charging; nanoparticle assembly; CS-AFM; KFM (en)
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  • CH - Švýcarská konfederace
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  • [191CAACA3A8E]
http://linked.open...i/riv/nazevZdroje
  • Diamond and Related Materials
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  • 24
http://linked.open...iv/tvurceVysledku
  • Kromka, Alexander
  • Rezek, Bohuslav
  • Ledinský, Martin
  • Verveniotis, Elisseos
http://linked.open...ain/vavai/riv/wos
  • 000303099700008
http://linked.open...n/vavai/riv/zamer
issn
  • 0925-9635
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.diamond.2011.10.002
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