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  • Cu doped ZnO polycrystalline pellets were synthesized with Cu concentrations varying from 2 to 10 wt% by a solid state reaction route (mixing of ZnO and CuO powders). By analyzing the XAS data, we found that at low Cu content most of the Cu atoms substitute for Zn inside the ZnO wurtzite lattice, while for higher Cu concentrations some unreacted CuO remains segregated from the Zn(1-x)Cu(x)O solid solution. Element-specific magnetic measurements were carried out by x-ray magnetic circular dichroism (XMCD) and compared to the results of ab initio calculations. The XMCD signal at the Cu K-edge originates from magnetic moments localized at Cu sites and, by monitoring the magnetic field dependence, we concur that these moments are associated with a paramagnetic state.
  • Cu doped ZnO polycrystalline pellets were synthesized with Cu concentrations varying from 2 to 10 wt% by a solid state reaction route (mixing of ZnO and CuO powders). By analyzing the XAS data, we found that at low Cu content most of the Cu atoms substitute for Zn inside the ZnO wurtzite lattice, while for higher Cu concentrations some unreacted CuO remains segregated from the Zn(1-x)Cu(x)O solid solution. Element-specific magnetic measurements were carried out by x-ray magnetic circular dichroism (XMCD) and compared to the results of ab initio calculations. The XMCD signal at the Cu K-edge originates from magnetic moments localized at Cu sites and, by monitoring the magnetic field dependence, we concur that these moments are associated with a paramagnetic state. (en)
Title
  • Cu doped ZnO pellets: study of structure and Cu specific magnetic properties
  • Cu doped ZnO pellets: study of structure and Cu specific magnetic properties (en)
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  • Cu doped ZnO pellets: study of structure and Cu specific magnetic properties
  • Cu doped ZnO pellets: study of structure and Cu specific magnetic properties (en)
skos:notation
  • RIV/68378271:_____/12:00384293!RIV13-GA0-68378271
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  • P(GAP108/11/0853), Z(AV0Z10100521)
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  • 50
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  • 129207
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  • RIV/68378271:_____/12:00384293
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  • ZnO; doping; structure; magnetism (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [4A432D6D3024]
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  • Journal of Physics-Condensed Matter
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  • 24
http://linked.open...iv/tvurceVysledku
  • Šipr, Ondřej
  • Rocca, F.
  • Bhatnagar, A. K.
  • Dalba, G.
  • Ramamoorthy, R. K.
  • Vachhani, P. S.
http://linked.open...ain/vavai/riv/wos
  • 000311891100019
http://linked.open...n/vavai/riv/zamer
issn
  • 0953-8984
number of pages
http://bibframe.org/vocab/doi
  • 10.1088/0953-8984/24/50/506001
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