About: Electron paramagnetic resonance studies of manganese centers in SrTiO3: Non-Kramers Mn3+ ions and spin-spin coupled Mn4+ dimers     Goto   Sponge   NotDistinct   Permalink

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  • An X- and Q-band electron paramagnetic resonance (EPR) study is reported on SrTiO3 single crystals doped with 0.5 at. % MnO. The EPR spectra originating from the S=2 ground state of the Mn3+ ions are shown to belong to three distinct types of Jahn-Teller centers. The ordering of the oxygen vacancies due to the reduction treatment of the samples and the consequent formation of an oxygen vacancy associated with the Mn3+ centers is explained in terms of the localized charge compensation. The EPR spectra of the SrTiO3:Mn crystals show the presence of next-nearest-neighbor exchange coupled Mn4+ pairs in the <110> directions.
  • An X- and Q-band electron paramagnetic resonance (EPR) study is reported on SrTiO3 single crystals doped with 0.5 at. % MnO. The EPR spectra originating from the S=2 ground state of the Mn3+ ions are shown to belong to three distinct types of Jahn-Teller centers. The ordering of the oxygen vacancies due to the reduction treatment of the samples and the consequent formation of an oxygen vacancy associated with the Mn3+ centers is explained in terms of the localized charge compensation. The EPR spectra of the SrTiO3:Mn crystals show the presence of next-nearest-neighbor exchange coupled Mn4+ pairs in the <110> directions. (en)
Title
  • Electron paramagnetic resonance studies of manganese centers in SrTiO3: Non-Kramers Mn3+ ions and spin-spin coupled Mn4+ dimers
  • Electron paramagnetic resonance studies of manganese centers in SrTiO3: Non-Kramers Mn3+ ions and spin-spin coupled Mn4+ dimers (en)
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  • Electron paramagnetic resonance studies of manganese centers in SrTiO3: Non-Kramers Mn3+ ions and spin-spin coupled Mn4+ dimers
  • Electron paramagnetic resonance studies of manganese centers in SrTiO3: Non-Kramers Mn3+ ions and spin-spin coupled Mn4+ dimers (en)
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  • RIV/68378271:_____/12:00378681!RIV13-TA0-68378271
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  • P(GAP108/12/1941), P(LM2011029), P(TA01010517), Z(AV0Z10100522)
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  • 10
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  • 133925
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  • RIV/68378271:_____/12:00378681
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  • electron paramagnetic resonance; X- and Q-band; SrTiO3 doped with Mn (en)
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  • US - Spojené státy americké
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  • [6D873427F604]
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  • Journal of Applied Physics
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  • 111
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  • Dejneka, Alexandr
  • Jastrabík, Lubomír
  • Lančok, Ján
  • Trepakov, Vladimír
  • Azamat, Dmitry
  • Badalyan, A. G.
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  • 000305363700126
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  • 0021-8979
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  • 10.1063/1.4723653
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