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  • Vapor pressure, liquid heat capacities, and phase change enthalpies and temperatures for technologically important organometallic precursor tetrakis(tert-butoxy)hafnium are reported. The vapor pressure was measured using the static method in the temperature range from 280 to 308 K. The standard vaporization enthalpy was derived from the temperature dependence of vapor pressure data. The liquid heat capacities were determined by Calvet calorimetry in the temperature range from 294 to 350 K. The enthalpy and temperature of fusion were measured by differential scanning calorimetry. The present study significantly extends and updates the information on physico-chemical properties for this material.
  • Vapor pressure, liquid heat capacities, and phase change enthalpies and temperatures for technologically important organometallic precursor tetrakis(tert-butoxy)hafnium are reported. The vapor pressure was measured using the static method in the temperature range from 280 to 308 K. The standard vaporization enthalpy was derived from the temperature dependence of vapor pressure data. The liquid heat capacities were determined by Calvet calorimetry in the temperature range from 294 to 350 K. The enthalpy and temperature of fusion were measured by differential scanning calorimetry. The present study significantly extends and updates the information on physico-chemical properties for this material. (en)
Title
  • Vapor pressure, heat capacities, and phase transitions of tetrakis(tert-butoxy)hafnium
  • Vapor pressure, heat capacities, and phase transitions of tetrakis(tert-butoxy)hafnium (en)
skos:prefLabel
  • Vapor pressure, heat capacities, and phase transitions of tetrakis(tert-butoxy)hafnium
  • Vapor pressure, heat capacities, and phase transitions of tetrakis(tert-butoxy)hafnium (en)
skos:notation
  • RIV/68378271:_____/11:00375616!RIV12-AV0-68378271
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(ME10049), Z(AV0Z10100521), Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika
  • Dec.
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  • 237902
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  • RIV/68378271:_____/11:00375616
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  • tetrakis(tert-butoxy)hafnium; MO precursor; vapor pressure; heat capacity; vaporization enthalpy; enthalpy of fusion (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [33663AB6DD05]
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  • Fluid Phase Equilibria
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http://linked.open...v/svazekPeriodika
  • 311
http://linked.open...iv/tvurceVysledku
  • Fulem, Michal
  • Růžička, K.
http://linked.open...ain/vavai/riv/wos
  • 000296999400004
http://linked.open...n/vavai/riv/zamer
issn
  • 0378-3812
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.fluid.2011.08.011
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