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  • Liquid crystalline (LC) material possessing two biphenyl moieties in the molecular core and lateral chlorine substitution far from the chiral chain has been studied by the broadband dielectric spectroscopy within frequency range 100 Hz-2 MHz. On cooling from the isotropic phase, the material possesses the frustrated smectic Q* (SmQ*) and the antiferroelectric smectic (SmCA*) phases within a broad temperature range. It has been confirmed by dielectric spectroscopy that the SmQ phase is closely related to SmCA* antiferroelectric phase. Only one relaxation process has been observed in the SmQ* phase, while in the SmCA* phase two relaxation are clearly detectable. It seems that mode found in the SmQ is connected with high frequency anti-phase mode observed in the SmCA* phase; this mode is weaker and faster than that in the SmCA* phase.
  • Liquid crystalline (LC) material possessing two biphenyl moieties in the molecular core and lateral chlorine substitution far from the chiral chain has been studied by the broadband dielectric spectroscopy within frequency range 100 Hz-2 MHz. On cooling from the isotropic phase, the material possesses the frustrated smectic Q* (SmQ*) and the antiferroelectric smectic (SmCA*) phases within a broad temperature range. It has been confirmed by dielectric spectroscopy that the SmQ phase is closely related to SmCA* antiferroelectric phase. Only one relaxation process has been observed in the SmQ* phase, while in the SmCA* phase two relaxation are clearly detectable. It seems that mode found in the SmQ is connected with high frequency anti-phase mode observed in the SmCA* phase; this mode is weaker and faster than that in the SmCA* phase. (en)
Title
  • Dielectric spectroscopy of the SmQ* phase
  • Dielectric spectroscopy of the SmQ* phase (en)
skos:prefLabel
  • Dielectric spectroscopy of the SmQ* phase
  • Dielectric spectroscopy of the SmQ* phase (en)
skos:notation
  • RIV/68378271:_____/11:00369921!RIV12-AV0-68378271
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(GA202/09/0047), P(GAP204/11/0723), P(IAA100100911), P(MEB050828), Z(AV0Z10100520)
http://linked.open...iv/cisloPeriodika
  • 11-12
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  • 194513
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  • RIV/68378271:_____/11:00369921
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  • chiral liquid crystal; dielectric spectroscopy; antiferroelectric phase; smectic Q phase; elaxation mode (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [C4284ED425BC]
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  • Phase Transitions
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  • 84
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  • Bubnov, Alexej
  • Hamplová, Věra
  • Kašpar, Miroslav
  • Ogrodnik, K.
  • Perkowski, P.
  • Piecek, W.
http://linked.open...ain/vavai/riv/wos
  • 000299705900021
http://linked.open...n/vavai/riv/zamer
issn
  • 0141-1594
number of pages
http://bibframe.org/vocab/doi
  • 10.1080/01411594.2011.580432
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