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  • Crystal structures of low temperature phases III, IV and V of rubidium zinc bromide have been determined by single crystal X-ray diffraction at 90 K, 85 K, and 30 K, respectively. The analysis of the structures in terms of symmetry-adapted modes of the high temperature prototype phase permits the identification of the modes responsible for each phase and to assess its thermal evolution. The primary mode responsible for the incommensurate and lock-in phases remains dominant throughout the whole transition sequence, maintaining its structure and slightly increasing its amplitude as tempera! ture decreases. The two monoclinic phases IV and V are presumably due to the instability of a second mode associated with a single active irreducible representation.
  • Crystal structures of low temperature phases III, IV and V of rubidium zinc bromide have been determined by single crystal X-ray diffraction at 90 K, 85 K, and 30 K, respectively. The analysis of the structures in terms of symmetry-adapted modes of the high temperature prototype phase permits the identification of the modes responsible for each phase and to assess its thermal evolution. The primary mode responsible for the incommensurate and lock-in phases remains dominant throughout the whole transition sequence, maintaining its structure and slightly increasing its amplitude as tempera! ture decreases. The two monoclinic phases IV and V are presumably due to the instability of a second mode associated with a single active irreducible representation. (en)
Title
  • Symmetry mode analysis of the phase transitions in Rb2ZnBr4.
  • Symmetry mode analysis of the phase transitions in Rb2ZnBr4. (en)
skos:prefLabel
  • Symmetry mode analysis of the phase transitions in Rb2ZnBr4.
  • Symmetry mode analysis of the phase transitions in Rb2ZnBr4. (en)
skos:notation
  • RIV/68378271:_____/10:00366892!RIV12-AV0-68378271
http://linked.open...avai/riv/aktivita
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  • Z(AV0Z10100521)
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  • 5
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  • 291371
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  • RIV/68378271:_____/10:00366892
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  • structure analysis; symmetry-adapted modes; structure refinement (en)
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  • DE - Spolková republika Německo
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  • [5CE9DA106CDB]
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  • Zeitschrift für Kristallographie
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  • 226
http://linked.open...iv/tvurceVysledku
  • Petříček, Václav
  • Perez-Mato, J. M.
  • Breczewski, T.
  • Orobengoa, D.
  • Zúniga, F. J.
http://linked.open...ain/vavai/riv/wos
  • 000291124200002
http://linked.open...n/vavai/riv/zamer
issn
  • 0044-2968
number of pages
http://bibframe.org/vocab/doi
  • 10.1524/zkri.2011.1367
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