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Description
| - The diamagnetic-paramagnetic and insulator-metal transitions in perovskites LnCoO3 (Ln=La, Y, rare earths) have been studied systematically. In a thermodynamic model, the transitions are interpreted as a two-step process, where first level are local excitations of Co3+ LS->S and second level is a stabilization of metallic phase with IS Co3+ due to electron transfer between LS/HS pairs.
- The diamagnetic-paramagnetic and insulator-metal transitions in perovskites LnCoO3 (Ln=La, Y, rare earths) have been studied systematically. In a thermodynamic model, the transitions are interpreted as a two-step process, where first level are local excitations of Co3+ LS->S and second level is a stabilization of metallic phase with IS Co3+ due to electron transfer between LS/HS pairs. (en)
- Přechody typu diamagnetismus-paramagnetismus a isolátor-kov v perovskitech LnCoO3 (Ln=La, Y, vzácné zeminy) byly systematicky studovány. Termodynamický model interpretuje přechody jako dvojstupňový proces, kde prvním krokem jsou lokální excitace Co3+ LS->HS a druhým krokem stabilizace metalické fáze s IS Co3+ v důsledku elektronového transferu mezi LS/HS páry. (cs)
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Title
| - Structural anomalies, spin transitions and charge disproportionation in LnCoO3.
- Structural anomalies, spin transitions and charge disproportionation in LnCoO3. (en)
- Strukturní anomalie, spinové přechody a nábojová disproporcionace v LnCoO3. (cs)
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skos:prefLabel
| - Structural anomalies, spin transitions and charge disproportionation in LnCoO3.
- Structural anomalies, spin transitions and charge disproportionation in LnCoO3. (en)
- Strukturní anomalie, spinové přechody a nábojová disproporcionace v LnCoO3. (cs)
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skos:notation
| - RIV/68378271:_____/08:00313199!RIV09-AV0-68378271
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA202/06/0051), Z(AV0Z10100521)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/68378271:_____/08:00313199
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - LnCoO3; neutron diffraction; thermal expansion; spin-state transition (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Applied Physics
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Knížek, Karel
- Jirák, Zdeněk
- Hejtmánek, Jiří
- André, G.
- Henry, P.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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is http://linked.open...avai/riv/vysledek
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