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  • 3,5-Dinitrobenzoate and picrate are light absorbing anions pertinent to indirect photometric detection of boron cluster anions in buffered methanolic background electrolytes (BGEs). Tris(hydroxymethyl)aminomethane and morpholine have been used as buffering bases, which eliminated baseline steps, and minimized the baseline noise. In methanolic BGEs, mobilities of boron cluster anions depend on both ionic constituents of the BGE buffer. This dependence can be explained by ion pair interaction of detected anions with BGE cations, which are not bonded into ion pairs with the BGE anions. The former ion pair interaction decreases sensitivity of the indirect photometric detection. (C) 2014 Elsevier B.V. All rights reserved.
  • 3,5-Dinitrobenzoate and picrate are light absorbing anions pertinent to indirect photometric detection of boron cluster anions in buffered methanolic background electrolytes (BGEs). Tris(hydroxymethyl)aminomethane and morpholine have been used as buffering bases, which eliminated baseline steps, and minimized the baseline noise. In methanolic BGEs, mobilities of boron cluster anions depend on both ionic constituents of the BGE buffer. This dependence can be explained by ion pair interaction of detected anions with BGE cations, which are not bonded into ion pairs with the BGE anions. The former ion pair interaction decreases sensitivity of the indirect photometric detection. (C) 2014 Elsevier B.V. All rights reserved. (en)
Title
  • Indirect photometric detection of boron cluster anions electrophoretically separated in methanol
  • Indirect photometric detection of boron cluster anions electrophoretically separated in methanol (en)
skos:prefLabel
  • Indirect photometric detection of boron cluster anions electrophoretically separated in methanol
  • Indirect photometric detection of boron cluster anions electrophoretically separated in methanol (en)
skos:notation
  • RIV/68081707:_____/14:00428340!RIV15-AV0-68081707
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • APR 2014
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 21198
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  • RIV/68081707:_____/14:00428340
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  • Boron cluster; Capillary electrophoresis; Indirect photometry (en)
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http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [97EFB05D369C]
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  • Journal of Chromatography A
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http://linked.open...v/svazekPeriodika
  • 1338
http://linked.open...iv/tvurceVysledku
  • Fojt, Lukáš
  • Vespalec, Radim
  • Vítová, Lada
http://linked.open...ain/vavai/riv/wos
  • 000334137200020
issn
  • 0021-9673
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.chroma.2014.02.060
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