About: Two-dimensional condensation of 5-fluorocytosine at the mercury electrode

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About: Two-dimensional condensation of 5-fluorocytosine at the mercury electrode Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Adsorption and two-dimensional (2D) condensation of 5-fluotocytosine on hanging mercury drop electrode is studied in this work. 5-fluorocytosine is an important derivative of cytosine which is widely used in pharmacology. The influence of concentration, temperature pH and electrolyte composition on the 2D condensation of 5-fluorocytosine was investigated by differential capacitance measurements. Three capacitance pits associated with the formation of 2D compact layers are evidenced. One film, formed at potential slightly negative from the potential of zero charge of the electrode, involves both neutral and protonated 5-fluorocytosine molecules. At highly negatively charged electrodes, dipole-induced orientation of 5-fluorocytosine leads to the formation of two additional 2D layers. One of them is found to result from the interaction of 5-fluorocytosine with acetic acid, present in the buffer electrolyte. Adsorption and two-dimensional (2D) condensation of 5-fluotocytosine on hanging mercury drop electrode is studied in this work. 5-fluorocytosine is an important derivative of cytosine which is widely used in pharmacology. The influence of concentration, temperature pH and electrolyte composition on the 2D condensation of 5-fluorocytosine was investigated by differential capacitance measurements. Three capacitance pits associated with the formation of 2D compact layers are evidenced. One film, formed at potential slightly negative from the potential of zero charge of the electrode, involves both neutral and protonated 5-fluorocytosine molecules. At highly negatively charged electrodes, dipole-induced orientation of 5-fluorocytosine leads to the formation of two additional 2D layers. One of them is found to result from the interaction of 5-fluorocytosine with acetic acid, present in the buffer electrolyte. (en)
Title	Two-dimensional condensation of 5-fluorocytosine at the mercury electrode Two-dimensional condensation of 5-fluorocytosine at the mercury electrode (en)
skos:prefLabel	Two-dimensional condensation of 5-fluorocytosine at the mercury electrode Two-dimensional condensation of 5-fluorocytosine at the mercury electrode (en)
skos:notation	RIV/68081707:_____/12:00440812!RIV15-GA0-68081707
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GAP205/10/2378), P(LC06035)
http://linked.open...iv/cisloPeriodika	SI
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Fojt, Lukáš Vetterl, Vladimír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Biofyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	175489
http://linked.open...ai/riv/idVysledku	RIV/68081707:_____/12:00440812
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	2D condensation; Hanging mercury drop electrode; 5-Fluorocytosine (en)
http://linked.open.../riv/klicoveSlovo	Hanging mercury drop electrode 5-Fluorocytosine 2D condensation
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[F0DF5015CA7A]
http://linked.open...i/riv/nazevZdroje	Electrochimica acta
http://linked.open...in/vavai/riv/obor	BO
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine. Induced organization of biomolecules at interfaces by interacting with electrically charged surfaces as a tool for medical diagnostics
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	73
http://linked.open...iv/tvurceVysledku	Fojt, Lukáš Vetterl, Vladimír Doneux, T.
http://linked.open...ain/vavai/riv/wos	000305261100022
issn	0013-4686
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.electacta.2011.12.061

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