About: The Rearrangement of 1-Methylcyclohex-1-ene during the Hydrodesulfurization of FCC Gasoline over Supported Co(Ni)Mo/Al2O3 Sulfide Catalysts: the Isolation and Identification of Branched Cyclic C7 Olefins

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About: The Rearrangement of 1-Methylcyclohex-1-ene during the Hydrodesulfurization of FCC Gasoline over Supported Co(Ni)Mo/Al2O3 Sulfide Catalysts: the Isolation and Identification of Branched Cyclic C7 Olefins Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	In the study of the simultaneous hydrodesulfurization of 1-benzothiophene and the olefin hydrogenation of 1-methylcyclohex-1-ene (1-MCH), we encountered a rearrangement of 1-MCH during the first step of catalytic hydrogenation, which yielded various branched cyclic olefins; mainly ethylcyclopentene and dimethylcyclopentene isomers. The volatile isomerization products were isolated directly from the diluted reaction mixture via the combination of chromatographic techniques including preparative gas chromatography, and were undoubtedly assigned by NMR spectroscopy. The precise identification of the isomerization products was required for a detailed kinetic study. In the study of the simultaneous hydrodesulfurization of 1-benzothiophene and the olefin hydrogenation of 1-methylcyclohex-1-ene (1-MCH), we encountered a rearrangement of 1-MCH during the first step of catalytic hydrogenation, which yielded various branched cyclic olefins; mainly ethylcyclopentene and dimethylcyclopentene isomers. The volatile isomerization products were isolated directly from the diluted reaction mixture via the combination of chromatographic techniques including preparative gas chromatography, and were undoubtedly assigned by NMR spectroscopy. The precise identification of the isomerization products was required for a detailed kinetic study. (en)
Title	The Rearrangement of 1-Methylcyclohex-1-ene during the Hydrodesulfurization of FCC Gasoline over Supported Co(Ni)Mo/Al2O3 Sulfide Catalysts: the Isolation and Identification of Branched Cyclic C7 Olefins The Rearrangement of 1-Methylcyclohex-1-ene during the Hydrodesulfurization of FCC Gasoline over Supported Co(Ni)Mo/Al2O3 Sulfide Catalysts: the Isolation and Identification of Branched Cyclic C7 Olefins (en)
skos:prefLabel	The Rearrangement of 1-Methylcyclohex-1-ene during the Hydrodesulfurization of FCC Gasoline over Supported Co(Ni)Mo/Al2O3 Sulfide Catalysts: the Isolation and Identification of Branched Cyclic C7 Olefins The Rearrangement of 1-Methylcyclohex-1-ene during the Hydrodesulfurization of FCC Gasoline over Supported Co(Ni)Mo/Al2O3 Sulfide Catalysts: the Isolation and Identification of Branched Cyclic C7 Olefins (en)
skos:notation	RIV/67985858:_____/14:00429923!RIV15-GA0-67985858
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GAP106/11/0902)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Kaluža, Luděk Storch, Jan Sýkora, Jan Karban, Jindřich
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	41509
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/14:00429923
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	hydrodesulfurization; olefin hydrogenation; branched cyclic olefins (en)
http://linked.open.../riv/klicoveSlovo	hydrodesulfurization branched cyclic olefins olefin hydrogenation
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[BE9B7F2290F3]
http://linked.open...i/riv/nazevZdroje	Reaction Kinetics Mechanism and Catalysis
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Unconventional Composition and Preparation of Sulfide Hydrotreating Catalysts
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	112
http://linked.open...iv/tvurceVysledku	Sýkora, Jan Žáček, Petr Kaluža, Luděk Karban, Jindřich Storch, Jan
http://linked.open...ain/vavai/riv/wos	000339378700004
issn	1878-5190
number of pages	12 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s11144-014-0709-z

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