About: Stereoselective Hydrogenation of Methyl Acetoacetate over Structurally Different Chiral Ruthenium Complexes

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Stereoselective Hydrogenation of Methyl Acetoacetate over Structurally Different Chiral Ruthenium Complexes Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Structurally different chiral ruthenium complexes were used in the asymmetric hydrogenation of methyl acetoacetate to methyl (R)-3-hydroxybutanoate. The naphthalene and dioxazole biphosphine structure variations revealed a strong effect on the reaction rate and the parameter of enantioselectivity. The highest optical yields were achieved with catalysts bearing two metal centers and comprising the quaternary ammonium ionic character. Structurally different chiral ruthenium complexes were used in the asymmetric hydrogenation of methyl acetoacetate to methyl (R)-3-hydroxybutanoate. The naphthalene and dioxazole biphosphine structure variations revealed a strong effect on the reaction rate and the parameter of enantioselectivity. The highest optical yields were achieved with catalysts bearing two metal centers and comprising the quaternary ammonium ionic character. (en)
Title	Stereoselective Hydrogenation of Methyl Acetoacetate over Structurally Different Chiral Ruthenium Complexes Stereoselective Hydrogenation of Methyl Acetoacetate over Structurally Different Chiral Ruthenium Complexes (en)
skos:prefLabel	Stereoselective Hydrogenation of Methyl Acetoacetate over Structurally Different Chiral Ruthenium Complexes Stereoselective Hydrogenation of Methyl Acetoacetate over Structurally Different Chiral Ruthenium Complexes (en)
skos:notation	RIV/67985858:_____/11:00369070!RIV12-AV0-67985858
http://linked.open...avai/predkladatel	Ústav chemických procesů Akademie Věd ČR, v.v.i.
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GD203/08/H032), Z(AV0Z40720504)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Klusoň, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	232357
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/11:00369070
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Ru–BINAP complex; enantioselectivity; optical yield (en)
http://linked.open.../riv/klicoveSlovo	enantioselectivity Ru–BINAP complex optical yield
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[37B8FB1BC951]
http://linked.open...i/riv/nazevZdroje	Reaction Kinetics Mechanism and Catalysis
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Advanced catalytic processes and materials
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	102
http://linked.open...iv/tvurceVysledku	Klusoň, Petr Floriš, T. Slater, M.
http://linked.open...ain/vavai/riv/wos	000297169300004
http://linked.open...n/vavai/riv/zamer	Investigation of multiphase reacting systems for the design of processes important in synthesis and preparation of novel materials, in energy production and in environmental protection
issn	1878-5190
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s11144-010-0256-1
is http://linked.open...avai/riv/vysledek of	Stereoselective Hydrogenation of Methyl Acetoacetate over Structurally Different Chiral Ruthenium Complexes Stereoselective Hydrogenation of Methyl Acetoacetate over Structurally Different Chiral Ruthenium Complexes

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software