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  • In the present analysis, a 1D approximation is used, assuming tacitly uniform accessibility of the working electrode and negligible transport resistances at the counter electrode. The Faradaic resistance of a redox couple O + ne (-) = R according to Butler-Volmer electrode kinetics is considered. The results of 1D theory are corrected for edge effects using the Oldham asymptote. The effect of convection at longer times is included using the recent model of a transient process for circular working electrodes in the LDC regime.
  • In the present analysis, a 1D approximation is used, assuming tacitly uniform accessibility of the working electrode and negligible transport resistances at the counter electrode. The Faradaic resistance of a redox couple O + ne (-) = R according to Butler-Volmer electrode kinetics is considered. The results of 1D theory are corrected for edge effects using the Oldham asymptote. The effect of convection at longer times is included using the recent model of a transient process for circular working electrodes in the LDC regime. (en)
Title
  • Voltage-Step Transient on Circular Electrodes
  • Voltage-Step Transient on Circular Electrodes (en)
skos:prefLabel
  • Voltage-Step Transient on Circular Electrodes
  • Voltage-Step Transient on Circular Electrodes (en)
skos:notation
  • RIV/67985858:_____/11:00364027!RIV13-GA0-67985858
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/08/0428), P(GA104/09/0972), Z(AV0Z40720504)
http://linked.open...iv/cisloPeriodika
  • 9
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 239500
http://linked.open...ai/riv/idVysledku
  • RIV/67985858:_____/11:00364027
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • ohmic loss; voltage-step transient; cottrell asymptote (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [B227150F5D3B]
http://linked.open...i/riv/nazevZdroje
  • Journal of Applied Electrochemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 41
http://linked.open...iv/tvurceVysledku
  • Wein, Ondřej
  • Tovčigrečko, Valentin
http://linked.open...ain/vavai/riv/wos
  • 000294477400008
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-891X
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10800-011-0288-x
is http://linked.open...avai/riv/vysledek of
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