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  • This study presents a computational fluid dynamics modeling approach to investigate the nucleation in the watersulfuric acid system in a flow tube. On the basis of an existing experimental setup we first establish the effect of convection on the flow profile. We describe the nucleation zone in detail and determine how flow rate and relative humidity affect its characteristics. Experimental nucleation rates are compared to rates gained from classical binary and kinetic nucleation theory as well as cluster activation theory. For low RH values, kinetic theory yields the best agreement with experimental results while binary nucleation best reproduces the experimental nucleation behavior at 50% relative humidity. Particle growth is modeled for an example case at 50% relative humidity. The final simulated diameter is very close to the experimental result.
  • This study presents a computational fluid dynamics modeling approach to investigate the nucleation in the watersulfuric acid system in a flow tube. On the basis of an existing experimental setup we first establish the effect of convection on the flow profile. We describe the nucleation zone in detail and determine how flow rate and relative humidity affect its characteristics. Experimental nucleation rates are compared to rates gained from classical binary and kinetic nucleation theory as well as cluster activation theory. For low RH values, kinetic theory yields the best agreement with experimental results while binary nucleation best reproduces the experimental nucleation behavior at 50% relative humidity. Particle growth is modeled for an example case at 50% relative humidity. The final simulated diameter is very close to the experimental result. (en)
Title
  • A Computational Fluid Dynamics Approach to Nucleation in the WaterSulfuric Acid System
  • A Computational Fluid Dynamics Approach to Nucleation in the WaterSulfuric Acid System (en)
skos:prefLabel
  • A Computational Fluid Dynamics Approach to Nucleation in the WaterSulfuric Acid System
  • A Computational Fluid Dynamics Approach to Nucleation in the WaterSulfuric Acid System (en)
skos:notation
  • RIV/67985858:_____/10:00346366!RIV11-AV0-67985858
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40720504)
http://linked.open...iv/cisloPeriodika
  • 31
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 244554
http://linked.open...ai/riv/idVysledku
  • RIV/67985858:_____/10:00346366
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • fluid dynamics modeling; kinetic nucleation theory; relative humidity (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [F5CF57C49944]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry A
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 114
http://linked.open...iv/tvurceVysledku
  • Brus, David
  • Hyvärinen, A.-P.
  • Lihavainen, H.
  • Kulmala, M.
  • Herrmann, E.
  • Stratmann, F.
  • Wilck, M.
http://linked.open...ain/vavai/riv/wos
  • 000280523500002
http://linked.open...n/vavai/riv/zamer
issn
  • 1089-5639
number of pages
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