About: Interplay Between Microscopic and Macroscopic Phase Separations in Ternary Polymer Melts: Insight from Mesoscale Modelling     Goto   Sponge   NotDistinct   Permalink

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  • We present a mesoscale computational study of a ternary polymer melt comprising of two immiscible homopolymers A and B, and a symmetric diblock copolymer AB. The system exhibits rich phase behavior such as microphase separations in the copolymer-rich region and macrophase separations in the homopolymer-rich region. We use Dissipative Particle Dynamics (DPD) and Dynamic mean-field Density Functional Theory (DDFT) to predict the phase behavior along a temperature–homopolymer volume fraction isopleth for an A/B/AB mesoscale system that mimics a real system of low molecular weight poly(dimethyl siloxane) (PDMS) and poly(ethyl ethylene) (PEE) homopolymers, and a nearly symmetric PDMS–PEE diblock copolymer.
  • We present a mesoscale computational study of a ternary polymer melt comprising of two immiscible homopolymers A and B, and a symmetric diblock copolymer AB. The system exhibits rich phase behavior such as microphase separations in the copolymer-rich region and macrophase separations in the homopolymer-rich region. We use Dissipative Particle Dynamics (DPD) and Dynamic mean-field Density Functional Theory (DDFT) to predict the phase behavior along a temperature–homopolymer volume fraction isopleth for an A/B/AB mesoscale system that mimics a real system of low molecular weight poly(dimethyl siloxane) (PDMS) and poly(ethyl ethylene) (PEE) homopolymers, and a nearly symmetric PDMS–PEE diblock copolymer. (en)
Title
  • Interplay Between Microscopic and Macroscopic Phase Separations in Ternary Polymer Melts: Insight from Mesoscale Modelling
  • Interplay Between Microscopic and Macroscopic Phase Separations in Ternary Polymer Melts: Insight from Mesoscale Modelling (en)
skos:prefLabel
  • Interplay Between Microscopic and Macroscopic Phase Separations in Ternary Polymer Melts: Insight from Mesoscale Modelling
  • Interplay Between Microscopic and Macroscopic Phase Separations in Ternary Polymer Melts: Insight from Mesoscale Modelling (en)
skos:notation
  • RIV/67985858:_____/09:00327183!RIV10-AV0-67985858
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1ET400720507), P(GA203/08/0094), P(KAN400720701), S, Z(AV0Z40720504)
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 320135
http://linked.open...ai/riv/idVysledku
  • RIV/67985858:_____/09:00327183
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • diblock copolymers; dissipative particle dynamics; microphase separation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [685A7F529105]
http://linked.open...i/riv/nazevZdroje
  • Fluid Phase Equilibria
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 283
http://linked.open...iv/tvurceVysledku
  • Lísal, Martin
  • Brennan, J. K.
  • Posel, Z.
http://linked.open...ain/vavai/riv/wos
  • 000268386800006
http://linked.open...n/vavai/riv/zamer
issn
  • 0378-3812
number of pages
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