About: Vapor–Liquid Equilibrium Coupled with Chemical Reaction (Transesterification)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A continuation of our study dealing with the investigation of chemical equilibrium superposed on vapour–liquid equilibrium (VLE) in fluid systems is presented. A transesterification reaction, namely the ethanol + propyl ethanoate <=> propanol + ethyl ethanoate reaction has been selected as a model. The reaction must be homogeneously catalyzed (potassium tert-butoxide). New experimental data on the quaternary system and the four non-reacting constituent binary subsystems were determined isothermally at 75 oC in a recirculation equilibrium still. The quaternary data will be correlated by the NRTL equation, with use of known parameters for the non-reacting binaries. A continuation of our study dealing with the investigation of chemical equilibrium superposed on vapour–liquid equilibrium (VLE) in fluid systems is presented. A transesterification reaction, namely the ethanol + propyl ethanoate <=> propanol + ethyl ethanoate reaction has been selected as a model. The reaction must be homogeneously catalyzed (potassium tert-butoxide). New experimental data on the quaternary system and the four non-reacting constituent binary subsystems were determined isothermally at 75 oC in a recirculation equilibrium still. The quaternary data will be correlated by the NRTL equation, with use of known parameters for the non-reacting binaries. (en) Výzkum chování kapalných soustav s chemickou rovnováhou superponovanou na rovnováhu fázovou. Jako model byla vybrána transesterifikační reakce, jmenovitě ethanol + propyl acetát <=> propanol + ethyl acetát. Nová experimentální data v tomto kvaternárním systému včetně všech 4 neragujících binárů byly měřeny isotermně při 75 C v cirkulačním přístroji. Data byla korelována pomocí rovnice NRTL na základě znalosti dat nereaktivních binárů. (cs)
Title	Vapor–Liquid Equilibrium Coupled with Chemical Reaction (Transesterification) Vapor–Liquid Equilibrium Coupled with Chemical Reaction (Transesterification) (en) Rovnováha kapalina-pára spojená s reakcí (transesterifikace) (cs)
skos:prefLabel	Vapor–Liquid Equilibrium Coupled with Chemical Reaction (Transesterification) Vapor–Liquid Equilibrium Coupled with Chemical Reaction (Transesterification) (en) Rovnováha kapalina-pára spojená s reakcí (transesterifikace) (cs)
skos:notation	RIV/67985858:_____/05:00028396!RIV06-AV0-67985858
http://linked.open.../vavai/riv/strany	s.68;69
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/03/1588), Z(AV0Z40720504)
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Aim, Karel Wichterle, Ivan
http://linked.open.../riv/druhVysledku	D - Článek ve sborníku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	548497
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/05:00028396
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	phase equilibria; chemical equilibria; transesterification (en)
http://linked.open.../riv/klicoveSlovo	chemical equilibria transesterification phase equilibria
http://linked.open...ontrolniKodProRIV	[CEDD4CCD3960]
http://linked.open...v/mistoKonaniAkce	Jurata
http://linked.open...i/riv/mistoVydani	-
http://linked.open...i/riv/nazevZdroje	Proceedings
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Phase equilibria in reacting systems
http://linked.open...UplatneniVysledku	2005
http://linked.open...iv/tvurceVysledku	Aim, Karel Wichterle, Ivan
http://linked.open...vavai/riv/typAkce	EUR - Evropská
http://linked.open.../riv/zahajeniAkce	2005-06-01 (xsd:date)
http://linked.open...n/vavai/riv/zamer	Investigation of multiphase reacting systems for the design of processes important in synthesis and preparation of novel materials, in energy production and in environmental protection
number of pages	2 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Neuveden
https://schema.org/isbn	83-920719-1-3
is http://linked.open...avai/riv/vysledek of	Vapor–Liquid Equilibrium Coupled with Chemical Reaction (Transesterification)

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