About: Studies on Sodium Lignosulfonate Depolymerization Over Al2O3 Supported Catalysts Loaded with Metals and Metal Oxides in a Continuous Flow Reactor     Goto   Sponge   NotDistinct   Permalink

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Description
  • The aim of this work was to study the how various heterogeneous catalysts perform upon lignosulfonate decomposition reactions. The main target of the study was to obtain extractable phenolic compounds as potential renewable chemicals for the production of fuel components and chemicals. The nature of the heterogeneous catalyst was found to have a great impact on the obtained product yields and the composition of the product mixture. Initially, a nickel–tungsten on alumina (NiW/Al2O3) reference catalyst was applied upon screening the influence of catalyst particle size and various reaction parameters. Significantly increasing product yields with decreasing catalyst particle size indicated that the lignosulfonate transformation takes place on the external catalyst surface due to large macromolecular structure of the feedstock. The contact time (space time velocity) and catalyst particle size were the most important factors influencing the selectivity profiles towards various products as well as the yields observed. The highest conversion to phenolics was obtained over inhouse-prepared NiO/Al2O3 and NiMo/Al2O3 catalysts with various NiO and MoO3 loadings.
  • The aim of this work was to study the how various heterogeneous catalysts perform upon lignosulfonate decomposition reactions. The main target of the study was to obtain extractable phenolic compounds as potential renewable chemicals for the production of fuel components and chemicals. The nature of the heterogeneous catalyst was found to have a great impact on the obtained product yields and the composition of the product mixture. Initially, a nickel–tungsten on alumina (NiW/Al2O3) reference catalyst was applied upon screening the influence of catalyst particle size and various reaction parameters. Significantly increasing product yields with decreasing catalyst particle size indicated that the lignosulfonate transformation takes place on the external catalyst surface due to large macromolecular structure of the feedstock. The contact time (space time velocity) and catalyst particle size were the most important factors influencing the selectivity profiles towards various products as well as the yields observed. The highest conversion to phenolics was obtained over inhouse-prepared NiO/Al2O3 and NiMo/Al2O3 catalysts with various NiO and MoO3 loadings. (en)
Title
  • Studies on Sodium Lignosulfonate Depolymerization Over Al2O3 Supported Catalysts Loaded with Metals and Metal Oxides in a Continuous Flow Reactor
  • Studies on Sodium Lignosulfonate Depolymerization Over Al2O3 Supported Catalysts Loaded with Metals and Metal Oxides in a Continuous Flow Reactor (en)
skos:prefLabel
  • Studies on Sodium Lignosulfonate Depolymerization Over Al2O3 Supported Catalysts Loaded with Metals and Metal Oxides in a Continuous Flow Reactor
  • Studies on Sodium Lignosulfonate Depolymerization Over Al2O3 Supported Catalysts Loaded with Metals and Metal Oxides in a Continuous Flow Reactor (en)
skos:notation
  • RIV/62243136:_____/13:GACR06CL!RIV14-GA0-62243136
http://linked.open...avai/predkladatel
http://linked.open...avai/riv/aktivita
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  • P(ED2.1.00/03.0071), P(GAP106/10/1733)
http://linked.open...iv/cisloPeriodika
  • 9-10
http://linked.open...vai/riv/dodaniDat
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  • 108580
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  • RIV/62243136:_____/13:GACR06CL
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  • Lignosulfonate, Methoxyphenols, Continuous flow reactor, Biomass valorization, (en)
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  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [BEF99547F1D4]
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  • Topics in Catalysis
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  • 56
http://linked.open...iv/tvurceVysledku
  • Horáček, Jan
  • Kubička, David
  • Hora, Lukáš
  • Larsson, William
  • Mikkola, Jyri-Pekka
  • Samikannu, Ajajkumar
  • Šťávova, Gabriela
http://linked.open...ain/vavai/riv/wos
  • 000320500200035
issn
  • 1022-5528
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s11244-013-0038-x
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