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  • Polyelectrolyte multilayers deposited on the wall of fused silica capillaries were for the first time used as stationary phases in open tubular ion chromatography. The multilayers are formed by flushing the capillaries with solutions of polyanions and polycations such as polydiallydimethylammonium chloride and dextran sulphate. Columns with several bi-layers are constructed and used in low pressure open tubular ion chromatohraphy of common inorganic anions and/or cations. We demonstrate separation of three common anions and five cations in a non-suppressed IC mode with sodium benzoate and tartaric acid eluents using a contactless conductometric detection. We further show that it is possible to prepare a bi-functional column that contains both anionic and cationic functional groups and can be used for simultaneous separation of anions and cations.
  • Polyelectrolyte multilayers deposited on the wall of fused silica capillaries were for the first time used as stationary phases in open tubular ion chromatography. The multilayers are formed by flushing the capillaries with solutions of polyanions and polycations such as polydiallydimethylammonium chloride and dextran sulphate. Columns with several bi-layers are constructed and used in low pressure open tubular ion chromatohraphy of common inorganic anions and/or cations. We demonstrate separation of three common anions and five cations in a non-suppressed IC mode with sodium benzoate and tartaric acid eluents using a contactless conductometric detection. We further show that it is possible to prepare a bi-functional column that contains both anionic and cationic functional groups and can be used for simultaneous separation of anions and cations. (en)
Title
  • Polyelectrolyte multilayers as stationary phases for open tubular ion chromatography
  • Polyelectrolyte multilayers as stationary phases for open tubular ion chromatography (en)
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  • Polyelectrolyte multilayers as stationary phases for open tubular ion chromatography
  • Polyelectrolyte multilayers as stationary phases for open tubular ion chromatography (en)
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  • RIV/62156489:43210/09:00142253!RIV10-GA0-43210___
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  • P(GA203/07/0983)
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  • 1
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  • 334152
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  • RIV/62156489:43210/09:00142253
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  • ion separation; polyelectrolyte; ion chromatography (en)
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  • NL - Nizozemsko
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  • [ECE337FBBA5C]
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  • Journal of Chromatography A
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  • 1216
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  • Kubáň, Vlastimil
  • Kubáň, Petr
  • Pelcová, Pavlína
  • Kiplagat, Isaac Kipkoech
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  • 0021-9673
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  • 43210
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