About: Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(#-NC)Ni(CN)2(#-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine}

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About: Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(#-NC)Ni(CN)2(#-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine} Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The bimetallic trinuclear complex [Cu(bappz)(mu-NC)Ni(CN)(2)(mu-CN)Cu(bappz)](ClO4)(2) (bappz = 1,4-bis(3-aminopropyl)piperazine) has been prepared from the reaction of [Cu(bappz)](ClO4)(2) and K-2[Ni(CN)(4)] in water and its crystal and molecular structure has been determined. The structure consists of a trinuclear [Cu(bappz)(mu-NC)Ni(CN)(2)(mu-CN)Cu(bappz)](2+) cation and two perchlorate anions. The bridging [Ni(CN)(4)](2-) anion is coordinated by two [Cu(bappz)](2+) cations through two cyano groups, providing a novel trinuclear structure with the Cu-(NC)-Ni-(CN)-Cu linkage. The nickel(II) ion is four-coordinated by carbon atoms from four cyano groups (two of them, in trans position, form a bridge) in a square planar arrangement, whereas both the copper(II) ions are five-coordinated by four bappz nitrogens and one cyanide nitrogen in a distorted square pyramidal geometry. The temperature dependence of magnetic susceptibility was measured for this compound over the range of 2-300 K. The magnetic inve The bimetallic trinuclear complex [Cu(bappz)(mu-NC)Ni(CN)(2)(mu-CN)Cu(bappz)](ClO4)(2) (bappz = 1,4-bis(3-aminopropyl)piperazine) has been prepared from the reaction of [Cu(bappz)](ClO4)(2) and K-2[Ni(CN)(4)] in water and its crystal and molecular structure has been determined. The structure consists of a trinuclear [Cu(bappz)(mu-NC)Ni(CN)(2)(mu-CN)Cu(bappz)](2+) cation and two perchlorate anions. The bridging [Ni(CN)(4)](2-) anion is coordinated by two [Cu(bappz)](2+) cations through two cyano groups, providing a novel trinuclear structure with the Cu-(NC)-Ni-(CN)-Cu linkage. The nickel(II) ion is four-coordinated by carbon atoms from four cyano groups (two of them, in trans position, form a bridge) in a square planar arrangement, whereas both the copper(II) ions are five-coordinated by four bappz nitrogens and one cyanide nitrogen in a distorted square pyramidal geometry. The temperature dependence of magnetic susceptibility was measured for this compound over the range of 2-300 K. The magnetic inve (en)
Title	Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(#-NC)Ni(CN)2(#-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine} Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(#-NC)Ni(CN)2(#-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine} (en)
skos:prefLabel	Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(#-NC)Ni(CN)2(#-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine} Synthesis, structure and magnetic properties of a trinuclear cyano-bridged complex [Cu(bappz)(#-NC)Ni(CN)2(#-CN)Cu(bappz)](ClO4)2 {bappz=1,4-bis(3-aminopropyl)piperazine} (en)
skos:notation	RIV/61989592:15410/03:00001506!RIV/2004/MSM/154104/N
http://linked.open.../vavai/riv/strany	1395-1399
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM 153100007), Z(MSM 153100008)
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Smékal, Zdeněk Trávníček, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Pedagogická fakulta
http://linked.open...dnocenehoVysledku	630090
http://linked.open...ai/riv/idVysledku	RIV/61989592:15410/03:00001506
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	trinuclear complex, copper(II), nickel(II), crystal structure, magnetic properties (en)
http://linked.open.../riv/klicoveSlovo	crystal structure magnetic properties copper(II) nickel(II) trinuclear complex
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[9E40E7C69D93]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	6
http://linked.open...iv/tvurceVysledku	Smékal, Zdeněk Trávníček, Zdeněk Marek, J. Mrozinski, J.
http://linked.open...n/vavai/riv/zamer	http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20153100008 http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20153100007
issn	1387-7003
number of pages	5 (xsd:int)
http://localhost/t...ganizacniJednotka	15410

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