About: Diaquabis(1,10-phenanthroline-k2 N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-k2 N,N')(thiodiglycolato-k2 O,O')manganese(II) tridecahydrate     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • The title compound, [Mn(C12H8N2)(2)(H2O)(2)](C4H4O4S).-[Mn(C4H4O4S)(C12H8N2)(2)].13H(2)O, contains one dianion of thiodiglycolic acid (tdga(2-)) and two independent manganese(II) moieties, viz. [Mn(phen)(2)(H2O)(2)](2+) and [Mn(tdga)(phen)(2)], where phen is 1,10-phenanthroline. The Mu(II) atoms are octahedrally coordinated by four N atoms of two bidentate phen ligands [Mn-N = 2.240 (2)-2.3222 (19) Angstrom] and either two water O atoms or two tdga carboxyl O atoms [Mn-O = 2.1214 (17)-2.1512 (17) Angstrom]. The tdga ligand chelates as an O,O'-bidentate ligand, forming an eight-membered ring with one Mn atom. The free tdga2- dianion is hydrogen bonded to an [Mn(phen)(2)(H2O)(2)](2+) ion, with O...O distances of 2.606 (2) and 2.649 (2) Angstrom. The crystal structure is further stabilized by an extensive network of hydrogen bonds involving 13 water molecules.
  • The title compound, [Mn(C12H8N2)(2)(H2O)(2)](C4H4O4S).-[Mn(C4H4O4S)(C12H8N2)(2)].13H(2)O, contains one dianion of thiodiglycolic acid (tdga(2-)) and two independent manganese(II) moieties, viz. [Mn(phen)(2)(H2O)(2)](2+) and [Mn(tdga)(phen)(2)], where phen is 1,10-phenanthroline. The Mu(II) atoms are octahedrally coordinated by four N atoms of two bidentate phen ligands [Mn-N = 2.240 (2)-2.3222 (19) Angstrom] and either two water O atoms or two tdga carboxyl O atoms [Mn-O = 2.1214 (17)-2.1512 (17) Angstrom]. The tdga ligand chelates as an O,O'-bidentate ligand, forming an eight-membered ring with one Mn atom. The free tdga2- dianion is hydrogen bonded to an [Mn(phen)(2)(H2O)(2)](2+) ion, with O...O distances of 2.606 (2) and 2.649 (2) Angstrom. The crystal structure is further stabilized by an extensive network of hydrogen bonds involving 13 water molecules. (en)
Title
  • Diaquabis(1,10-phenanthroline-k2 N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-k2 N,N')(thiodiglycolato-k2 O,O')manganese(II) tridecahydrate
  • Diaquabis(1,10-phenanthroline-k2 N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-k2 N,N')(thiodiglycolato-k2 O,O')manganese(II) tridecahydrate (en)
skos:prefLabel
  • Diaquabis(1,10-phenanthroline-k2 N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-k2 N,N')(thiodiglycolato-k2 O,O')manganese(II) tridecahydrate
  • Diaquabis(1,10-phenanthroline-k2 N,N')manganese(II) thiodiglycolate bis(1,10-phenanthroline-k2 N,N')(thiodiglycolato-k2 O,O')manganese(II) tridecahydrate (en)
skos:notation
  • RIV/61989592:15410/03:00001448!RIV/2004/MSM/154104/N
http://linked.open.../vavai/riv/strany
  • M429-M431
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 153100008)
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 603677
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15410/03:00001448
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • RAY CRYSTAL-STRUCTURES, MANGANESE(II) COMPLEXES, MOLECULAR-STRUCTURE, CATALYTIC ACTIVITY, ACID, PHEN=1,10-PHENANTHROLINE, THIODIACETATE (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DK - Dánské království
http://linked.open...ontrolniKodProRIV
  • [0A2E9052DFD1]
http://linked.open...i/riv/nazevZdroje
  • Acta Crystallographica Section C-crystal Structure Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 59
http://linked.open...iv/tvurceVysledku
  • Trávníček, Zdeněk
  • Marek, J.
  • Kopel, Pavel
http://linked.open...n/vavai/riv/zamer
issn
  • 0108-2701
number of pages
http://localhost/t...ganizacniJednotka
  • 15410
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 112 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software