About: Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)]

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.sciencedirect.com/science/article/pii/S0277538713008036
Description	A series of square-planar nickel(II) benzylpiperazine-dithiocarbamato (bpdtc; 1-4) and thiomorpholinedithiocarbamato (tmdtc; 5-8) complexes of the composition [NiX(ndtc)(PPh3)] (X symbolizes Cl for I and 5, Br for 2 and 6, I for 3 and 7, or NCS for 4 and 8) was prepared and thoroughly characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy, mass spectrometry, molar conductivity and magnetochemical measurements, and by single-crystal X-ray analysis (for complex 1). The solution behaviour study of selected representatives (1, 4, 5 and 8) in various solvents (acetone, acetonitrile, methanol (MeOH), N,N'-dimethylformamide (DMF), chloroform, nitromethane, dimethyl sulfoxide (DMSO), MeOH/water mixture (1:1 v/v)) by a combination of NMR and UV-Vis spectroscopy, mass spectrometry and single-crystal X-ray analysis showed that the complexes decompose back to the synthetic precursors, involving the [Ni(ndtc)(2)] species, in DMF and DMSO, while they dissolve without a change in their composition in the remaining solvents. A series of square-planar nickel(II) benzylpiperazine-dithiocarbamato (bpdtc; 1-4) and thiomorpholinedithiocarbamato (tmdtc; 5-8) complexes of the composition [NiX(ndtc)(PPh3)] (X symbolizes Cl for I and 5, Br for 2 and 6, I for 3 and 7, or NCS for 4 and 8) was prepared and thoroughly characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy, mass spectrometry, molar conductivity and magnetochemical measurements, and by single-crystal X-ray analysis (for complex 1). The solution behaviour study of selected representatives (1, 4, 5 and 8) in various solvents (acetone, acetonitrile, methanol (MeOH), N,N'-dimethylformamide (DMF), chloroform, nitromethane, dimethyl sulfoxide (DMSO), MeOH/water mixture (1:1 v/v)) by a combination of NMR and UV-Vis spectroscopy, mass spectrometry and single-crystal X-ray analysis showed that the complexes decompose back to the synthetic precursors, involving the [Ni(ndtc)(2)] species, in DMF and DMSO, while they dissolve without a change in their composition in the remaining solvents. (en)
Title	Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)] Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)] (en)
skos:prefLabel	Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)] Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)] (en)
skos:notation	RIV/61989592:15310/14:33152282!RIV15-MSM-15310___
http://linked.open...avai/riv/aktivita	P S
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0058), P(EE2.3.20.0017), S
http://linked.open...iv/cisloPeriodika	February 2014
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Drahoš, Bohuslav Trávníček, Zdeněk Štarha, Pavel Pastorek, Richard
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	13241
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/14:33152282
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Mass spectrometry; NMR; Solution study; Crystal structure; Dithiocarbamate; Nickel(II) complexes (en)
http://linked.open.../riv/klicoveSlovo	Solution study Nickel(II) complexes Crystal structure Mass spectrometry NMR Dithiocarbamate
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[6EF021462572]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Regional Centre of Advanced Technologies and Materials Research team development of the Regional Centre of Advanced Technologies and Materials
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	69
http://linked.open...iv/tvurceVysledku	Trávníček, Zdeněk Štarha, Pavel Drahoš, Bohuslav Pastorek, Richard
http://linked.open...ain/vavai/riv/wos	000331502500024
issn	0277-5387
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.poly.2013.11.041
http://localhost/t...ganizacniJednotka	15310

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