About: Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://pubs.acs.org/doi/ipdf/10.1021/nn4024027
Description	Graphene derivatives containing covalently bound halogens (graphene halides) represent promising two-dimensional systems having interesting physical and chemical properties. The attachment of halogen atoms to sp(2) carbons changes the hybridization state to sp(3), which has a principal impact on electronic properties and local structure of the material. The fully fluorinated graphene derivative, fluorographene (graphene fluoride, C1F1), is the thinnest insulator and the only stable stoichiometric graphene halide (C1X1). In this review, we discuss structural properties, syntheses, chemistry, stabilities, and electronic properties of fluorographene and other partially fluorinated, chlorinated, and brominated graphenes. Remarkable optical, mechanical, vibrational, thermodynamic, and conductivity properties of graphene halides are also explored as well as the properties of rare structures including multilayered fluorinated graphenes, iodine-doped graphene, and mixed graphene halides. Finally, patterned halogenation is presented as an interesting approach for generating materials with applications in the field of graphene-based electronic devices. Graphene derivatives containing covalently bound halogens (graphene halides) represent promising two-dimensional systems having interesting physical and chemical properties. The attachment of halogen atoms to sp(2) carbons changes the hybridization state to sp(3), which has a principal impact on electronic properties and local structure of the material. The fully fluorinated graphene derivative, fluorographene (graphene fluoride, C1F1), is the thinnest insulator and the only stable stoichiometric graphene halide (C1X1). In this review, we discuss structural properties, syntheses, chemistry, stabilities, and electronic properties of fluorographene and other partially fluorinated, chlorinated, and brominated graphenes. Remarkable optical, mechanical, vibrational, thermodynamic, and conductivity properties of graphene halides are also explored as well as the properties of rare structures including multilayered fluorinated graphenes, iodine-doped graphene, and mixed graphene halides. Finally, patterned halogenation is presented as an interesting approach for generating materials with applications in the field of graphene-based electronic devices. (en)
Title	Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives (en)
skos:prefLabel	Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives (en)
skos:notation	RIV/61989592:15310/13:33147800!RIV14-GA0-15310___
http://linked.open...avai/predkladatel	Přírodovědecká fakulta
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0058), P(EE2.3.20.0017), P(EE2.3.30.0041), P(GBP208/12/G016)
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Zbořil, Radek Otyepka, Michal Karlický, František Kasibhatta, Kumara Ramanatha Datta
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	77013
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/13:33147800
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	1ST-PRINCIPLES; GRAPHANE; OXIDE; FUNCTIONALIZATION; FLUOROGRAPHENE; MOLECULAR-DYNAMICS; GRAPHITE FLUORIDE; MAGNETIC-PROPERTIES; SURFACE-FLUORINATED GRAPHENE; INFRARED SPECTRAL SIGNATURES (en)
http://linked.open.../riv/klicoveSlovo	OXIDE 1ST-PRINCIPLES MAGNETIC-PROPERTIES MOLECULAR-DYNAMICS FLUOROGRAPHENE FUNCTIONALIZATION GRAPHANE GRAPHITE FLUORIDE INFRARED SPECTRAL SIGNATURES SURFACE-FLUORINATED GRAPHENE
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[58F4870D02B8]
http://linked.open...i/riv/nazevZdroje	ACS Nano
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Controlling structure and function of biomolecules at the molecular scale: theory meets experiment Podpora vytváření excelentních výzkumných týmů a intersektorální mobility na Univerzitě Palackého v Olomouci II. Regional Centre of Advanced Technologies and Materials Research team development of the Regional Centre of Advanced Technologies and Materials
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	7
http://linked.open...iv/tvurceVysledku	Otyepka, Michal Zbořil, Radek Karlický, František Kasibhatta, Kumara Ramanatha Datta
http://linked.open...ain/vavai/riv/wos	000323810600004
issn	1936-0851
number of pages	31 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/nn4024027
http://localhost/t...ganizacniJednotka	15310

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